Experimental Bench-marking of Pu Electronic Structure

Lawrence Livermore National Laboratory

关键词: ACCELERATION;    ELECTRON CORRELATION;    ELECTRONIC STRUCTURE;    IMPLEMENTATION;    PHOTOELECTRON SPECTROSCOPY;    SAFETY;    SCHEDULES;    SPECTROSCOPY;    TESTING;   

DOI  :  10.2172/921756
RP-ID  :  UCRL-TR-233240
PID  :  OSTI ID: 921756
Others  :  TRN: US200806%%140

学科分类：化学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

Our plan is to do Ce (as a Pu surrogate) this year and be ready to do Pu next year. The Fano (Spin-resolved Photoelectron Spectroscopy) measurements are essential to testing electron correlation in the occupied 5f states. BIS (Bremstrahlung Isochromat Spectroscopy or high energy Inverse Photoelectron Spectroscopy) experiments are crucial to a quantitative determination of the 5f unoccupied density of states (5f-UDOS). The 5f UDOS is the key to differentiation between a myriad of models of 5f electronic structure. During this time, we will work to converge to a solution for the Pu safety issues, with the plan to implement these in the next FY. Acceleration of this schedule and implementation of the safety plan in this FY will require a very significant increase in funding. Ultimately, results from the Pu experiments will be fed into calculations performed by P. Soderlind, A. Landa, and others.