A Site Wide Perspective on Uranium Geochemistry at the Hanford Site

Zachara, John M. ; Brown, Christopher F. ; Christensen, J. N. ; Davis, Jim A. ; Dresel, P. Evan ; Liu, Chongxuan ; Kelly, S. D. ; McKinley, James P. ; Serne, R. Jeffrey ; Um, Wooyong

关键词: GEOCHEMISTRY;    PLUMES;    URANIUM;    RADIONUCLIDE MIGRATION;    HANFORD RESERVATION;    SOILS;    GROUND WATER;    SITE CHARACTERIZATION Uranium;    U(VI);    Environmental Molecular Sciences Laboratory;   

DOI  :  10.2172/920206
RP-ID  :  PNNL-17031
PID  :  OSTI ID: 920206
Others  :  Other: 4597
Others  :  830403000
Others  :  TRN: US0807378

美国|英语

来源: SciTech Connect

【 摘 要 】

Uranium (U) is an important risk-driving contaminant at the Hanford Site. Over 200,000 kg have been released to the vadose zone over the course of site operations, and a number of vadose zone and groundwater plumes containing the uranyl cation [UO22+, U(VI)] have been identified. U is recognized to be of moderate-to-high mobility, conditions dependent. The site is currently making decisions on several of these plumes with long-lasting implications, and others are soon to come. Uranium is one of nature’s most intriguing and chemically complex elements. The fate and transport of U(VI) has been studied over the long lifetime of the Hanford Site by various contractors, along with the Pacific Northwest National Laboratory (PNNL) and its collaborators. Significant research has more recently been contributed by the national scientific community with support from the U.S. Department of Energy’s (DOE) Office of Science through its Environmental Remediation Sciences Division (ERSD). This report represents a first attempt to integrate these findings into a cohesive view of the subsurface geochemistry of U at the Hanford Site. The objective is to inform all interested Hanford parties about the in-ground inventory of U and its geochemical behavior. This report also comments on the prospects for the development of a robust generic model to more accurately forecast future U(VI) migration at different Hanford waste sites, along with further research necessary to reach this goal.