Status of initial testing of the H2SO4 section of the ILS experiment.

Moore, Robert Charles ; Parma, Edward J., Jr. ; Gelbard, Fred

关键词: BENCH-SCALE EXPERIMENTS;    CATALYSTS;    DESIGN;    HEAT TRANSFER;    HYDROGEN;    MODIFICATIONS;    SILICON CARBIDES;    STEELS;    SULFURIC ACID;    TEFLON;    TESTING Nuclear reactors-Hydrogen content.;    Sulfuric acid;   

DOI  :  10.2172/945174
RP-ID  :  SAND2007-7841
PID  :  OSTI ID: 945174
Others  :  TRN: US0900814

美国|英语

来源: SciTech Connect

【 摘 要 】

A sulfuric acid catalytic decomposer section was assembled and tested for the Integrated Laboratory Scale experiments of the Sulfur-Iodine Thermochemical Cycle. This cycle is being studied as part of the U. S. Department of Energy Nuclear Hydrogen Initiative. Tests confirmed that the 54-inch long silicon carbide bayonet could produce in excess of the design objective of 100 liters/hr of SO{sub 2} at 2 bar. Furthermore, at 3 bar the system produced 135 liters/hr of SO{sub 2} with only 31 mol% acid. The gas production rate was close to the theoretical maximum determined by equilibrium, which indicates that the design provides adequate catalyst contact and heat transfer. Several design improvements were also implemented to greatly minimize leakage of SO{sub 2} out of the apparatus. The primary modifications were a separate additional enclosure within the skid enclosure, and replacement of Teflon tubing with glass-lined steel pipes.