Hydrologic Resources Management Program and Underground Test Area Project FY 2006 Progress Report

Culham, H W ; Eaton, G F ; Genetti, V ; Hu, Q ; Kersting, A B ; Lindvall, R E ; Moran, J E ; Blasiyh Nuno, G A ; Powell, B A ; Rose, T P ; Singleton, M J ; Williams, R W ; Zavarin, M ; Zhao, P

关键词: 07 ISOTOPES AND RADIATION SOURCES;    CARBONATES;    DESORPTION;    GEOLOGIC SURVEYS;    GOETHITE;    MANAGEMENT;    MONITORING;    NATIONAL SECURITY;    NEVADA TEST SITE;    OXIDATION;    PROGRESS REPORT;    RADIONUCLIDE MIGRATION;    SAMPLING;    SECURITY;    SORPTION;    TESTING;    TUFF;   

DOI  :  10.2172/945573
RP-ID  :  LLNL-TR-404620
PID  :  OSTI ID: 945573
Others  :  TRN: US0901214

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来源: SciTech Connect

【 摘 要 】

This report describes FY 2006 technical studies conducted by the Chemical Biology and Nuclear Science Division (CBND) at Lawrence Livermore National Laboratory (LLNL) in support of the Hydrologic Resources Management Program (HRMP) and the Underground Test Area Project (UGTA). These programs are administered by the U.S. Department of Energy, National Nuclear Security Administration, Nevada Site Office (NNSA/NSO) through the Defense Programs and Environmental Restoration Divisions, respectively. HRMP-sponsored work is directed toward the responsible management of the natural resources at the Nevada Test Site (NTS), enabling its continued use as a staging area for strategic operations in support of national security. UGTA-funded work emphasizes the development of an integrated set of groundwater flow and contaminant transport models to predict the extent of radionuclide migration from underground nuclear testing areas at the NTS. The report is organized on a topical basis and contains four chapters that highlight technical work products produced by CBND. However, it is important to recognize that most of this work involves collaborative partnerships with the other HRMP and UGTA contract organizations. These groups include the Energy and Environment Directorate at LLNL (LLNL-E&E), Los Alamos National Laboratory (LANL), the Desert Research Institute (DRI), the U.S. Geological Survey (USGS), Stoller-Navarro Joint Venture (SNJV), and National Security Technologies (NSTec). Chapter 1 is a summary of FY 2006 sampling efforts at near-field 'hot' wells at the NTS, and presents new chemical and isotopic data for groundwater samples from four near-field wells. These include PM-2 and U-20n PS 1DDh (CHESHIRE), UE-7ns (BOURBON), and U-19v PS No.1ds (ALMENDRO). Chapter 2 is a summary of the results of chemical and isotopic measurements of groundwater samples from three UGTA environmental monitoring wells. These wells are: ER-12-4 and U12S located in Area 12 on Rainier Mesa and USGS HGH No.2 WW2 located in Yucca Flat. In addition, three springs were sampled White Rock Spring and Captain Jack Spring in Area 12 on Rainier Mesa and Topopah Spring in Area 29. Chapter 3 is a compilation of existing noble gas data that has been reviewed and edited to remove inconsistencies in presentation of total vs. single isotope noble gas values reported in the previous HRMP and UGTA progress reports. Chapter 4 is a summary of the results of batch sorption and desorption experiments performed to determine the distribution coefficients (Kd) of Pu(IV), Np(V), U(VI), Cs and Sr to zeolitized tuff (tuff confining unit, TCU) and carbonate (lower carbonate aquifer, LCA) rocks in synthetic NTS groundwater Chapter 5 is a summary of the results of a series of flow-cell experiments performed to examine Np(V) and Pu(V) sorption to and desorption from goethite. Np and Pu desorption occur at a faster rate and to a greater extent than previously reported. In addition, oxidation changes occurred with the Pu whereby the surface-sorbed Pu(IV) was reoxidized to aqueous Pu(V) during desorption.