PROBABILITY BASED CORROSION CONTROL FOR HIGH LEVEL WASTE TANKS: INTERIM REPORT

Hoffman, E ; Karthik Subramanian, K

关键词: CARBON STEELS;    CHEMISTRY;    CORROSION;    HYDROXIDES;    IMPLEMENTATION;    LIQUID WASTES;    NITRATES;    NITRITES;    POLARIZATION;    PROBABILITY;    STRESS CORROSION;    TANKS;    TESTING;    WASTES;   

DOI  :  10.2172/927900
RP-ID  :  WSRC-STI-2007-00712
PID  :  OSTI ID: 927900
Others  :  TRN: US200816%%707

学科分类：材料科学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

Controls on the solution chemistry (minimum nitrite and hydroxide concentrations) are in place to prevent the initiation and propagation of pitting and stress corrosion cracking in high level waste (HLW) tanks. These controls are based upon a series of experiments performed on carbon steel coupons in simulated waste solutions. An experimental program was undertaken to investigate reducing the minimum molar nitrite concentration required to confidently inhibit pitting. A statistical basis to quantify the probability of pitting for the tank wall, when exposed to various dilute solutions, is being developed. Electrochemical and coupon testing are being performed within the framework of the statistical test matrix to determine the minimum necessary inhibitor concentrations and develop a quantitative model to predict pitting propensity. A subset of the original statistical test matrix was used to develop an applied understanding of the corrosion response of the carbon steel in the various environments. The interim results suggest that there exists some critical nitrite concentration that sufficiently inhibits against localized corrosion mechanisms due to nitrates/chlorides/sulfates, beyond which further nitrite additions are unnecessary. The combination of visual observation and the cyclic potentiodynamic polarization scans indicate the potential for significant inhibitor reductions without consequence specifically at nitrate concentrations near 1 M. The complete data sets will be used to determine the statistical basis to confidently inhibit against pitting using nitrite inhibition with the current pH controls. Once complete, a revised chemistry control program will be devised based upon the probability of pitting specifically for dilute solutions which will allow for tank specific chemistry control implementation.