Final work plan : supplemental upward vapor intrusion investigation at the former CCC/USDA grain storage facility in Hanover, Kansas.

LaFreniere, L. M. ; Environmental Science Division

关键词: AGRICULTURE;    ANL;    CARBON TETRACHLORIDE;    CHLOROFORM;    FUMIGANTS;    GEOCHEMISTRY;    INDOORS;    SAMPLING;    SITE CHARACTERIZATION;    SOILS;    STORAGE;    STORAGE FACILITIES;   

DOI  :  10.2172/946679
RP-ID  :  ANL/EVS/AGEM/TR-08-14
PID  :  OSTI ID: 946679
Others  :  TRN: US200903%%977

学科分类：环境科学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility at the northeastern edge of the city of Hanover, Kansas, from 1950 until the early 1970s. During this time, commercial grain fumigants containing carbon tetrachloride were in common use by the grain storage industry to preserve grain in their facilities. In February 1998, trace to low levels of carbon tetrachloride (below the maximum contaminant level [MCL] of 5.0 {micro}g/L) were detected in two private wells near the former grain storage facility at Hanover, as part of a statewide USDA private well sampling program that was implemented by the Kansas Department of Health and Environment (KDHE) near former CCC/USDA facilities. In 2007, the CCC/USDA conducted near-surface soil sampling at 61 locations and also sampled indoor air at nine residences on or adjacent to its former Hanover facility to address the residents concerns regarding vapor intrusion. Low levels of carbon tetrachloride were detected at four of the nine homes. The results were submitted to the KDHE in October 2007 (Argonne 2007). On the basis of the results, the KDHE requested sub-slab sampling and/or indoor air sampling (KDHE 2007). This Work Plan describes, in detail, the proposed additional scope of work requested by the KDHE and has been developed as a supplement to the comprehensive site investigation work plan that is pending (Argonne 2008). Indoor air samples collected previously from four homes at Hanover were shown to contain the carbon tetrachloride at low concentrations (Table 2.1). It cannot be concluded from these previous data that the source of the detected carbon tetrachloride is vapor intrusion attributable to former grain storage operations of the CCC/USDA at Hanover. The technical objective of the vapor intrusion investigation described here is to assess the risk to human health due to the potential for upward migration of carbon tetrachloride and chloroform into four homes located on or adjacent to the former CCC/USDA facility. The technical objective will be accomplished by collecting sub-slab vapor samples. The preliminary data collected during the July 2007 investigation did not fully address the source of or migration pathway for the carbon tetrachloride detected in the four homes. The scope of work proposed here will generate additional data needed to help evaluate whether the source of the detected carbon tetrachloride is vapor intrusion attributable to activities of the CCC/USDA. The additional vapor sampling at Hanover will be performed, on behalf of the CCC/USDA, by the Environmental Science Division of Argonne National Laboratory and H&P Mobile Geochemistry of San Diego (http://www.handpmg.com). Argonne is a nonprofit, multidisciplinary research center operated by UChicago Argonne, LLC, for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an interagency agreement with DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. The professional staff members of H&P Mobile Geochemistry are nationally leading experts in soil gas sampling and vapor intrusion investigations.