Photoinitiated Processes in Small Hydrides Final Technical Report DE-FG02-04ER15509

Wittig, Curt

关键词: HYDRIDES;    PHOTOCHEMISTRY;    CHEMICAL REACTION KINETICS;   

DOI  :  10.2172/952390
RP-ID  :  DOE/ER/15509-1
PID  :  OSTI ID: 952390
Others  :  TRN: US201006%%802

学科分类：化学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

This grant was in effect for a quite long time: 1984-2008. This period saw a broad range of research activities transpire in my group, and these enlisted the participation of many students, postdoctorals, and visitors. The earliest participants have since enjoyed full careers: faculty members here and abroad, government laboratories, successful entrepreneurs, and so on. Some have even retired! Consequently, during the past few months I have repeatedly asked myself: how can a coherent, readable report be prepared that covers so long a period of time and so varied a collection of projects? On the one hand, the work has evolved — a sensible progression of experimental techniques and strategies, as well as a parallel deepening of our theoretical understanding. On the other hand, there is a distinctive¬ness to many of the projects that enables them to be arranged into groups. In the end a compromise was struck. Areas and topics that received the most focused attention are identified. Our main contributions and how they relate to the field of chemical dynamics, in general, are organized according to these groups. Publications are listed but not explained per se, as this would produce a manifestly unreadable document. They are all available in PDF format upon request. Following this, brief synopses are presented for each of the groupings — getting straight to the point, but with the wisdom of hindsight.