科技报告详细信息
Catalysts for Dehydrogenation of ammonia boranes | |
Heinekey, Dennis M.1  | |
[1] Univ. of Washington, Seattle, WA (United States) | |
关键词: hydrogen storage catalysis; | |
DOI : 10.2172/1165735 RP-ID : DOE-UW--15057 PID : OSTI ID: 1165735 |
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学科分类:再生能源与代替技术 | |
美国|英语 | |
来源: SciTech Connect | |
【 摘 要 】
Several effective homogeneous catalysts for the dehydrogenation of amine boranes have been developed. The best catalyst uses an iridium complex, and is capable of dehydrogenating H3NBH3 (AB) and CH3NH2BH3 (MeAB) at comparable rates. Thermodynamic measurements using this catalyst demonstrate that the dehydrogenation of AB and MeAB is substantially exothermic, which has important implications for regeneration.
【 预 览 】
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