PEP Run Report for Simulant Shakedown/Functional Testing

Josephson, Gary B. ; Geeting, John GH ; Bredt, Ofelia P. ; Burns, Carolyn A. ; Golovich, Elizabeth C. ; Guzman-Leong, Consuelo E. ; Kurath, Dean E. ; Sevigny, Gary J.

关键词: AR FACILITIES;    RADIOACTIVE WASTE FACILITIES;    PROCESS DEVELOPMENT UNITS;    RADIOACTIVE WASTE PROCESSING;    LEACHING;    ULTRAFILTRATION;    WASHING;    SODIUM HYDROXIDES;    TESTING;   

DOI  :  10.2172/970759
RP-ID  :  PNNL-18823
RP-ID  :  WTP-RPT-190 Rev 0
PID  :  OSTI ID: 970759
Others  :  Other: 830403000
Others  :  TRN: US1000925

学科分类：核能源与工程

美国|英语

来源: SciTech Connect

【 摘 要 】

Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Waste Treatment Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes." The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct injection of steam to accelerate the leach process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP-1, the 19-M NaOH is added to un-concentrated waste slurry (3-8 wt% solids), while for leaching in UFP-2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before the addition of caustic. In both scenarios, following the caustic leach, the slurry was then concentrated to 17 wt% and washed with inhibited water to remove NaOH and other soluble salts. Next, the slurry was oxidatively leached using sodium permanganate to solubilize chrome. The slurry was then washed to remove the dissolved chrome and concentrated.