TANK 7 CHARACTERIZATION AND WASHING STUDIES

Lambert, D. ; Pareizs, J. ; Click, D.

关键词: AR FACILITIES;    SAVANNAH RIVER PLANT;    PUREX PROCESS;    SLUDGES;    CHEMICAL COMPOSITION;    WASHING;    OXALATES;    REMOVAL;    DISSOLUTION;    FLAMMABILITY;    PERFORMANCE TESTING;    RADIOACTIVE WASTE PROC;   

DOI  :  10.2172/973191
RP-ID  :  SRNL-STI-2009-00774
PID  :  OSTI ID: 973191
Others  :  TRN: US1001829

学科分类：核能源与工程

美国|英语

来源: SciTech Connect

【 摘 要 】

A 3-L PUREX sludge sample from Tank 7 was characterized and then processed through a series of inhibited water washes to remove oxalate, sodium, and other soluble ions. Current plans use Tank 7 as one of the feed sources for Sludge Batch 7 (SB7). Tank 7 is high in oxalate due to the oxalic acid cleaning of the sludge heels from Tanks 5 and 6 and subsequent transfer to Tank 7. Ten decant and nine wash cycles were performed over a 47 day period at ambient temperature. Initially, seven decants and seven washes were completed based on preliminary estimates of the number of wash cycles required to remove the oxalate in the sludge. After reviewing the composition data, SRNL recommended the completion of 2 or 3 more decant/wash cycles to ensure all of the sodium oxalate had redissolved. In the first 7 washes, the slurry oxalate concentration was 12,300 mg/kg (69.6% oxalate removal compared to 96.1% removal of the other soluble ions). After all ten decants were complete, the slurry oxalate concentration was 3,080 mg/kg (89.2% oxalate removal compared to 99.0% of the other soluble ions). The rate of dissolution of oxalate increased significantly with subsequent washes until all of the sodium oxalate had been redissolved after seven decant/wash cycles. The measured oxalate concentrations agreed very well with LWO predictions for washing of the Tank 7 sample. Highlights of the analysis and washing of the Tank 7 sample include: (1) Sodium oxalate was detected in the as-received filtered solids. 95% of the oxalate was insoluble (undissolved) in the as-received slurry. (2) No sodium oxalate was detected in the post-wash filtered solids. (3) Sodium oxalate is the last soluble species that redissolves during washing with inhibited water. In order to significantly reduce the sodium oxalate concentration, the sludge must be highly washed, leaving the other soluble anions and cations (including sodium) very low in concentration. (4) The post-wash slurry had 1% of the soluble anions and cations remaining, with the exception of sodium and oxalate, for which the percentages were 2.8% and 10.8% respectively. The post-wash sodium concentration was 9.25 wt% slurry total solids basis and 0.15 M supernate. (5) The settling rate of slurry was very fast allowing the completion of one decant/wash cycle each day. (6) The measured yield stress of as-received (6.42 wt% undissolved solids) and post-wash (7.77 wt% undissolved solids) slurry was <1 Pa. For rapidly settling slurries, it can be hard to measure the yield stress of the slurry so this result may be closer to the supernate result than the slurry. The recommended strategy for developing the oxalate target for sludge preparation for Sludge Batch 7 includes the following steps: (1) CPC simulant testing to determine the percent oxalate destruction and acid mix needed to produce a predicted redox of approximately 0.2 Fe{sup +2}/{Sigma}Fe in a SME product while meeting all DWPF processing constraints. (2) Perform a DWPF melter flammability assessment to ensure that the additional carbon in the oxalate together with other carbon sources will not lead to a flammability issue. (3) Perform a DWPF glass paper assessment to ensure the glass produced will meet all DWPF glass limits due to the sodium concentration in the sludge batch. The testing would need to be repeated if a significant CPC processing change, such as an alternative reductant to formic acid, is implemented.