RESULTS FOR THE SECOND QUARTER 2010 TANK 50 WAC SLURRY SAMPLE: CHEMICAL AND RADIONUCLIDE CONTAMINANT RESULTS

Reigel, M. ; Bibler, N.

关键词: AR FACILITIES;    AQUEOUS SOLUTIONS;    LIQUID WASTES;    RADIOISOTOPES;    SAMPLING;    SENSITIVITY;    SOLUBILITY;    LOW-LEVEL RADIOACTIVE WASTES;    CHEMICAL COMPOSITION;    RADIOACTIVE WASTE PROCESSING;   

DOI  :  10.2172/992237
RP-ID  :  SRNL-STI-2010-00437
PID  :  OSTI ID: 992237
Others  :  TRN: US1007765

学科分类：核能源与工程

美国|英语

来源: SciTech Connect

【 摘 要 】

This report details the chemical and radionuclide contaminant results for the characterization of the 2010 Second Quarter sampling of Tank 50 for the Saltstone Waste Acceptance Criteria (WAC).1 Information from this characterization will be used by Liquid Waste Operations (LWO) to support the transfer of low-level aqueous waste from Tank 50 to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50 Waste Characterization System. The following conclusions are drawn from the analytical results provided in this report: (1) The concentrations of the reported chemical and radioactive contaminants were less than their respective WAC targets or limits unless noted in this section. (2) The reported detection limits for {sup 94}Nb and {sup 144}Ce are above both the established and requested limits from References 4 and 6. (3) The reported detection limits for {sup 247}Cm and {sup 249}Cf are above the requested limits from Reference 4. However, they are below the limits established in Reference 6. (4) The reported detection limit for Isopar L is greater than the limit from Table 3 of the WAC. (5) A measurable concentration of Norpar 13 is present in the sample. The reported concentration is greater than the requested limit from Table 4 and Attachment 8.2 of the WAC. (6) Isopar L and Norpar 13 have limited solubility in aqueous solutions making it difficult to obtain consistent and reliable sub-samples. The values reported in this memo are the concentrations in the sub-sample as detected by the GC/MS; however, the results may not accurately represent the concentrations of the analytes in Tank 50. (7) The detection limit for isopropanol has been lowered from 0.5 mg/L to 0.25 mg/L{sup 7}. This revised limit now satisfies the limit in Table 4 of the WAC.