ANALYSIS OF PASSIVATED SURFACES FOR MASS SPECTROMETER INLET SYSTEMS BY AUGER ELECTRON AND X-RAY PHOTOELECTRON SPECTROSCOPY

Ajo, H. ; Clark, E.

关键词: AUGER ELECTRON SPECTROSCOPY;    COATINGS;    CONTAINERS;    ELECTRON MICROSCOPES;    ELECTRONS;    ELECTROPOLISHING;    LAYERS;    MASS SPECTROMETERS;    MORPHOLOGY;    OXIDES;    PASSIVATION;    SILICON;    STAINLESS STEELS;    STORAGE;    SURFACE TREATMENTS;    SURFACES;    THIC;   

DOI  :  10.2172/1005019
RP-ID  :  SRNL-STI-2010-00394
PID  :  OSTI ID: 1005019
Others  :  TRN: US201106%%55

学科分类：材料科学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

Stainless steel coupons approximately 0.5' in diameter and 0.125' thick were passivated with five different surface treatments and an untreated coupon was left as a control. These surface treatments are being explored for use in tritium storage containers. These coupons were made to allow surface analysis of the surface treatments using well-know surface analysis techniques. Depth profiles using Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) were performed on these coupons to characterize the surface and near surface regions. Scanning electron microscope (SEM) images were collected as well. All of the surface treatments studied here appear to change the surface morphology dramatically, as evidenced by lack of tool marks on the treated samples. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7-0.9 nm thick) as well as the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E's silicon coating appears to be on the order of 200 nm thick.