Self-degradable Cementitious Sealing Materials

Sugama, T. ; Butcher, T., Lance Brothers, Bour, D.

关键词: ADDITIVES;    BREAKDOWN;    CALCIUM SILICATES;    CELLULOSE;    CEMENTS;    DISSOLUTION;    FLY ASH;    GEOTHERMAL SYSTEMS;    HEATING;    HYDRATES;    HYDRATION;    POROSITY;    SEALING MATERIALS;    SODIUM;    SODIUM SILICATES;    THERMAL DEGRADATION;    WATER Cementitious;    slag;   

DOI  :  10.2172/993804
RP-ID  :  BNL--94308-2010-IR
PID  :  OSTI ID: 993804
Others  :  Other: EB4005020
Others  :  TRN: US201101%%224

学科分类：再生能源与代替技术

美国|英语

来源: SciTech Connect

【 摘 要 】

A self-degradable alkali-activated cementitious material consisting of a sodium silicate activator, slag, Class C fly ash, and sodium carboxymethyl cellulose (CMC) additive was formulated as one dry mix component, and we evaluated its potential in laboratory for use as a temporary sealing material for Enhanced Geothermal System (EGS) wells. The self-degradation of alkali-activated cementitious material (AACM) occurred, when AACM heated at temperatures of {ge}200 C came in contact with water. We interpreted the mechanism of this water-initiated self-degradation as resulting from the in-situ exothermic reactions between the reactants yielded from the dissolution of the non-reacted or partially reacted sodium silicate activator and the thermal degradation of the CMC. The magnitude of self-degradation depended on the CMC content; its effective content in promoting degradation was {ge}0.7%. In contrast, no self-degradation was observed from CMC-modified Class G well cement. For 200 C-autoclaved AACMs without CMC, followed by heating at temperatures up to 300 C, they had a compressive strength ranging from 5982 to 4945 psi, which is {approx}3.5-fold higher than that of the commercial Class G well cement; the initial- and final-setting times of this AACM slurry at 85 C were {approx}60 and {approx}90 min. Two well-formed crystalline hydration phases, 1.1 nm tobermorite and calcium silicate hydrate (I), were responsible for developing this excellent high compressive strength. Although CMC is an attractive, as a degradation-promoting additive, its addition to both the AACM and the Class G well cement altered some properties of original cementitious materials; among those were an extending their setting times, an increasing their porosity, and lowering their compressive strength. Nevertheless, a 0.7% CMC-modified AACM as self-degradable cementitious material displayed the following properties before its breakdown by water; {approx}120 min initial- and {approx}180 min final-setting times at 85 C, and 1825 to 1375 psi compressive strength with 51.2 to 55.0% porosity up to 300 C.