Nanocrystal-enabled solid state bonding.

San Diego State University, San Diego, CA ; Puskar, Joseph David ; Tikare, Veena ; Garcia Cardona, Cristina (San Diego State University, San Diego, CA) ; Reece, Mark ; Brewer, Luke N. (Naval Postgraduate School, Monterey, CA) ; Holm, Elizabeth Ann

关键词: BONDING;    DIFFUSION;    GOLD;    SILVER;    NANOSTRUCTURES;    HOT PRESSING;    SHEAR PROPERTIES;    SINTERING;    MATHEMATICAL MODELS Semiconductors-Bonding.;    Semiconductor nanocrystals.;    Nanocrystals.;   

DOI  :  10.2172/992782
RP-ID  :  SAND2010-7013
PID  :  OSTI ID: 992782
Others  :  TRN: US201022%%509

美国|英语

来源: SciTech Connect

【 摘 要 】

In this project, we performed a preliminary set of sintering experiments to examine nanocrystal-enabled diffusion bonding (NEDB) in Ag-on-Ag and Cu-on-Cu using Ag nanoparticles. The experimental test matrix included the effects of material system, temperature, pressure, and particle size. The nanoparticle compacts were bonded between plates using a customized hot press, tested in shear, and examined post mortem using microscopy techniques. NEDB was found to be a feasible mechanism for low-temperature, low-pressure, solid-state bonding of like materials, creating bonded interfaces that were able to support substantial loads. The maximum supported shear strength varied substantially within sample cohorts due to variation in bonded area; however, systematic variation with fabrication conditions was also observed. Mesoscale sintering simulations were performed in order to understand whether sintering models can aid in understanding the NEDB process. A pressure-assisted sintering model was incorporated into the SPPARKS kinetic Monte Carlo sintering code. Results reproduce most of the qualitative behavior observed in experiments, indicating that simulation can augment experiments during the development of the NEDB process. Because NEDB offers a promising route to low-temperature, low-pressure, solid-state bonding, we recommend further research and development with a goal of devising new NEDB bonding processes to support Sandia's customers.