科技报告详细信息
ZINC MITIGATION INTERIM REPORT - THERMODYNAMIC STUDY
Korinko, P.
关键词: COBALT;    COPPER;    DEPOSITION;    FURNACES;    GASES;    HYDROGEN;    LITHIUM;    MITIGATION;    MOLYBDENUM;    PHASE DIAGRAMS;    TESTING;    THERMODYNAMICS;    WATER;    ZINC;   
DOI  :  10.2172/1025514
RP-ID  :  SRNL-STI-2010-00473
PID  :  OSTI ID: 1025514
Others  :  TRN: US201120%%766
学科分类:再生能源与代替技术
美国|英语
来源: SciTech Connect
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【 摘 要 】

An experimental program was initiated in order to develop and validate conditions that will effectively trap Zn vapors that are released during extraction. The proposed work is broken down into three tasks. The first task is to determine the effectiveness of various pore sizes of filter elements. The second task is to determine the effect of filter temperature on zinc vapor deposition. The final task is to determine whether the zinc vapors can be chemically bound. The approach for chemically binding the zinc vapors has two subtasks, the first is a review of literature and thermodynamic calculations and the second is an experimental approach using the best candidates. This report details the results of the thermodynamic calculations to determine feasibility of chemically binding the zinc vapors within the furnace module, specifically the lithium trap (1). A review of phase diagrams, literature, and thermodynamic calculations was conducted to determine if there are suitable materials to capture zinc vapor within the lithium trap of the extraction basket. While numerous elements exist that form compounds with zinc, many of these also form compounds with hydrogen or the water that is present in the TPBARs. This relatively comprehensive review of available data indicates that elemental cobalt and copper and molybdenum trioxide (MoO3) may have the requisite properties to capture zinc and yet not be adversely affected by the extraction gases and should be considered for testing.

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