Radiation-Induced Segregation and Phase Stability in Candidate Alloys for the Advanced Burner Reactor

Gary S. Was ; Brian D. Wirth

关键词: ALLOYS;    BURNERS;    DIFFUSION;    ELECTRONS;    GRAIN BOUNDARIES;    INTERSTITIALS;    IRRADIATION;    PHASE STABILITY;    POINT DEFECTS;    PRODUCTION;    PROTONS;    RADIATIONS;    RECOMBINATION;    SATURATION;    SEGREGATION;    SIMULATION;    TRANSPORT Radiation induced segregation;    kinetic lattice monte carlo;    inverse Kirkendall;   

DOI  :  10.2172/1014433
RP-ID  :  Final Report 1
PID  :  OSTI ID: 1014433
Others  :  Other: NERI 07-015
Others  :  TRN: US1103059

美国|英语

来源: SciTech Connect

【 摘 要 】

Major accomplishments of this project were the following: 1) Radiation induced depletion of Cr occurs in alloy D9, in agreement with that observed in austenitic alloys. 2) In F-M alloys, Cr enriches at PAG grain boundaries at low dose (<7 dpa) and at intermediate temperature (400?��C) and the magnitude of the enrichment decreases with temperature. 3) Cr enrichment decreases with dose, remaining enriched in alloy T91 up to 10 dpa, but changing to depletion above 3 dpa in HT9 and HCM12A. 4) Cr has a higher diffusivity than Fe by a vacancy mechanism and the corresponding atomic flux of Cr is larger than Fe in the opposite direction to the vacancy flux. 5) Cr concentration at grain boundaries decreases as a result of vacancy transport during electron or proton irradiation, consistent with Inverse Kirkendall models. 6) Inclusion of other point defect sinks into the KLMC simulation of vacancy-mediated diffusion only influences the results in the low temperature, recombination dominated regime, but does not change the conclusion that Cr depletes as a result of vacancy transport to the sink. 7) Cr segregation behavior is independent of Frenkel pair versus cascade production, as simulated for electron versus proton irradiation conditions, for the temperatures investigated. 8) The amount of Cr depletion at a simulated planar boundary with vacancy-mediated diffusion reaches an apparent saturation value by about 1 dpa, with the precise saturation concentration dependent on the ratio of Cr to Fe diffusivity. 9) Cr diffuses faster than Fe by an interstitial transport mechanism, and the corresponding atomic flux of Cr is much larger than Fe in the same direction as the interstitial flux. 10) Observed experimental and computational results show that the radiation induced segregation behavior of Cr is consistent with an Inverse Kirkendall mechanism.