OXALATE MASS BALANCE DURING CHEMICAL CLEANING IN TANK 6F

Poirier, M. ; Fink, S.

关键词: AR FACILITIES;    ANIONS;    CARBON DIOXIDE;    CATIONS;    CLEANING;    CLOSURES;    IRON;    MANGANESE;    MASS BALANCE;    NICKEL;    NITRIC ACID;    OXALATES;    OXALIC ACID;    PERSONNEL;    REMOVAL;    SAMPLING;    SAVANNAH RIVER PLANT;    SLUDGES;    SODIUM;    TANKS;   

DOI  :  10.2172/1025572
RP-ID  :  SRNL-STI-2011-00438
PID  :  OSTI ID: 1025572
Others  :  TRN: US1104984

学科分类：核能源与工程

美国|英语

来源: SciTech Connect

【 摘 要 】

The Savannah River Remediation (SRR) is preparing Tank 6F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRR personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 6F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate. Some conclusions from this work are: (1) Approximately 65% of the oxalate added as oxalic acid was removed with the decanted liquid. (2) Approximately 1% of the oxalate (added to the tank as oxalic acid) formed precipitates with compounds such as nickel, manganese, sodium, and iron (II), and was dissolved with nitric acid. (3) As much as 30% of the oxalate may have decomposed forming carbon dioxide. The balance does not fully account for all the oxalate added. The offset represents the combined uncertainty in the analyses and sampling.