SALTSTONE 2QCY11 TCLP RESULTS

Eibling, R.

关键词: AR FACILITIES;    ACTINIDES;    ANTIMONY;    ARSENIC;    BARIUM;    BENZENE;    BERYLLIUM;    CADMIUM;    CHEMISTRY;    CHROMIUM;    GROUTING;    LEACHING;    MERCURY;    NICKEL;    PHENOLS;    RADIOACTIVE WASTE PROCESSING;    REMOVAL;    SANITARY LANDFILLS;    SELENIUM;    SILVER;    SOLID WASTES;    SOLVENT EXTRACTION;    TANKS;    THALLIUM;    WASTE MANAGEMENT;    WASTES;   

DOI  :  10.2172/1023620
RP-ID  :  SRNL-STI-2011-00406
PID  :  OSTI ID: 1023620
Others  :  TRN: US201119%%150

美国|英语

来源: SciTech Connect

【 摘 要 】

The Saltstone Production Facility (SPF) receives waste from Tank 50H for treatment. In the second quarter of the 2011 calendar year (2QCY11), Tank 50H accepted transfers of approximately 15 kgal from the Effluent Treatment Project (ETP), approximately 2 kgal from Tank 710 - the H-Canyon General Purpose Evaporator, approximately 63 kgal from the HCanyon Super Kukla campaign, approximately 370 kgal from the Actinide Removal Process/Modular Caustic Side Solvent Extraction Unit (ARP/MCU) Decontaminated Salt Solution Hold Tank (DSS-HT), and approximately 10 kgal from other sources. The Saltstone Grout Sampling plan provides the South Carolina Department of Health and Environmental Control (SCDHEC) with the chemical and physical characterization strategy for the salt solution which is to be disposed of in the Z-Area Solid Waste Landfill (SWLF). During operation, samples were collected from Tank 50H and grout samples prepared to determine the non-hazardous nature of the grout to meet the requirements of the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24(b) and R.61-79.268.48(a). Savannah River National Laboratory (SRNL) was asked to prepare saltstone from samples of Tank 50H obtained April 5, 2011 during 2QCY11 to determine the non-hazardous nature of the grout. The samples were cured and shipped to Babcock & Wilcox Technical Services Group-Radioisotope and Analytical Chemistry Laboratory (B&W TSG-RACL) to perform the Toxic Characteristic Leaching Procedure (TCLP) and subsequent extract analysis on saltstone samples for the analytes required for the quarterly analysis saltstone sample. In addition to the eight toxic metals - arsenic, barium, cadmium, chromium, mercury, lead, selenium and silver - analytes included the underlying hazardous constituents (UHC) antimony, beryllium, nickel, and thallium which could not be eliminated from analysis by process knowledge. B&W TSGRACL provided subsamples to GEL Laboratories, LLC for analysis for the UHCs benzene, phenols and total and amenable cyanide.