Iron Phosphate Glass-Containing Hanford Waste Simulant

Sevigny, Gary J. ; Kimura, Marcia L. ; Fischer, Christopher M. ; Schweiger, Michael J. ; Kim, Dong-Sang

关键词: AR FACILITIES;    CONSTRUCTION;    DESIGN;    EFFICIENCY;    GLASS;    IMPLEMENTATION;    IRON;    IRON PHOSPHATES;    PROCESSING;    RESOLUTION;    SAVANNAH RIVER PLANT;    SULFATES;    TANKS;    TESTING;    VIABILITY;    VITRIFICATION;    WASTE PROCESSING;    WASTES Research scale melter;    iron phosphate;    low activity waste;    glass;   

DOI  :  10.2172/1025092
RP-ID  :  PNNL-20670
PID  :  OSTI ID: 1025092
Others  :  Other: EY4049110
Others  :  TRN: US1104850

学科分类：核能源与工程

美国|英语

来源: SciTech Connect

【 摘 要 】

Resolution of the nation???s high level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron phosphate-based glass with a selected waste composition that is high in sulfates (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis as related to the implementation of phosphate-based glasses for Hanford low activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, and Mo-Sci Corporation.