Design and Characterization of Photoelectrodes from First Principles

Ogitsu, T ; Wood, B ; Choi, W ; Huda, M ; Wei, S

关键词: DESIGN;    EFFICIENCY;    ELECTRODES;    FOCUSING;    OPTIMIZATION;    PERFORMANCE;    SYNTHESIS;    WATER;   

DOI  :  10.2172/1043650
RP-ID  :  LLNL-TR-557515
PID  :  OSTI ID: 1043650
Others  :  TRN: US201214%%152

学科分类：材料科学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

Although significant performance improvements have been realized since the first demonstration of sunlight-driven water splitting in 1972, mainstream adoption of photoelectrochemical (PEC) cells remains limited by an absence of cost-effective electrodes that show simultaneously high conversion efficiency and good durability. Here we outline current and future efforts to use advanced theoretical techniques to guide the development of a durable, high-performance PEC electrode material. Working in close collaboration with experimental synthesis and characterization teams, we use a twofold approach focusing on: (1) rational design of novel high-performance electrode materials; and (2) characterization and optimization of the electrode-electrolyte interface.