Potential Benefits of Manmade Opals Demonstrated for First Time (Fact Sheet)

关键词: CAPACITY;    CONFINEMENT;    DIFFUSION;    LASERS;    LIGHT SCATTERING;    MANAGEMENT;    NATIONAL RENEWABLE ENERGY LABORATORY;    OPALS;    OPTICAL PROPERTIES;    PERFORMANCE;    TRAPPING;    WAVELENGTHS MANMADE OPALS;    OPTOELECTRONIC MATERIALS;    NIR LIGHT TRAPPING;    DISORDERED INVERSE OPALS;    Chemical and Material Sciences;   

DOI  :  10.2172/1045719
RP-ID  :  NREL/FS-5900-53385
PID  :  OSTI ID: 1045719
Others  :  TRN: US201215%%205

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来源: SciTech Connect

【 摘 要 】

NREL experiments show that disordered inverse opals significantly scatter and trap near-infrared light, with possible impact on optoelectronic materials. Inverse opals, familiar in the form of brilliantly colored opal gemstones, are a class of materials that has astounding optical properties. Scientists have been exploring the ability of inverse opals to manipulate light in the hopes of harnessing this capacity for advanced technologies such as displays, detectors, lasers, and photovoltaics. A research group at the National Renewable Energy Laboratory (NREL) discovered that man-made inverse opal films containing significant morphological disorder exhibit substantial light scattering, consequently trapping wavelengths in the near-infrared (NIR), which is important to a number of technologies. This discovery is the first experimental evidence to validate a 2005 theoretical model predicting the confinement of light in such structures, and it holds great promise for improving the performance of technologies that rely on careful light control. This breakthrough also makes possible optoelectronic technologies that use a range of low-cost molecular and semiconductor species that otherwise absorb light too weakly to be useful. The disordered inverse opal architecture validates the theoretical model that predicts the diffusion and confinement of light in such structures. Electrochemically deposited CdSe inverse opal films containing significant morphological disorder exhibit substantial light scattering and consequent NIR light trapping. This discovery holds promise for NIR light management in optoelectronic technologies, particularly those involving weakly absorbing molecular and semiconductor photomaterials.