SRNL PHASE II SHELF LIFE STUDIES - SERIES 1 ROOM TEMPERATURE AND HIGH RELATIVE HUMIDITY

Mickalonis, J. ; Duffey, J.

关键词: CHEMISTRY;    CHLORIDES;    CONTAINERS;    CORROSION;    DEFECTS;    HUMIDITY;    LANL;    MIXTURES;    MOISTURE;    MONITORS;    PLUTONIUM;    PLUTONIUM OXIDES;    SAVANNAH RIVER;    STAINLESS STEELS;    STORAGE;    STRESS CORROSION;    TESTING;   

DOI  :  10.2172/1050621
RP-ID  :  SRNL-STI-2012-00530
PID  :  OSTI ID: 1050621
Others  :  TRN: US201218%%1049

学科分类：材料科学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

The Savannah River National Laboratory (SRNL) Phase II, Series 1 shelf-life corrosion testing for the Department of Energy Standard 3013 container is presented and discussed in terms of the localized corrosion behavior of Type 304 stainless steel in contact with moist plutonium oxide and chloride salt mixtures and the potential impact to the 3013 inner container. This testing was designed to address the influence of temperature, salt composition, initial salt moisture, residual stress and type of oxide/salt contact on the relative humidity inside a 3013 container and the initiation and propagation of localized corrosion, especially stress corrosion cracking. The integrated plan is being conducted by Los Alamos National Laboratory and SRNL. SRNL is responsible for conducting a corrosion study in small scale vessels containing plutonium oxide and chloride salts under conditions of humidity, temperature and oxide/salt compositions both within the limits of 3013 storage conditions as well as beyond the 3013 storage requirements to identify margins for minimizing the initiation of stress corrosion cracking. These worst case conditions provide data that bound the material packaged in 3013 containers. Phase I of this testing was completed in 2010. The Phase II, Series 1 testing was performed to verify previous results from Phase I testing and extend our understanding about the initiation of stress corrosion cracking and pitting that occur in 304L under conditions of room temperature, high humidity, and a specific plutonium oxide/salt chemistry. These results will aid in bounding the safe storage conditions of plutonium oxides in 3013 containers. A substantial change in the testing was the addition of the capability to monitor relative humidity during test exposure. The results show that under conditions of high initial moisture ({approx}0.5 wt%) and room temperature stress corrosion cracking occurred in 304L teardrop coupons in contact with the oxide/salt mixture at times as short as 85 days. In all cases, the cracking appeared to be associated with pitting or localized general corrosion. Crack initiation at other sites, such as surface imperfections or inclusions, cannot be excluded. Cracks appear in most cases to initiate through an intergranular mode and transition to a transgranular mode.