Final Report: Process Models of the Equilibrium Size & State of Organic/Inorganic Aerosols for the Development of Large Scale Atmospheric Models & the Analysis of Field Data

Wexler, Anthony Stein¹  Clegg, Simon Leslie¹ 

[1] UC Davis

关键词: Atmospheric aerosols;    climate change;    atmospheric chemistry;   

DOI  :  10.2172/1097441
RP-ID  :  DOE-UCDavis-ER64530
PID  :  OSTI ID: 1097441

学科分类：环境科学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

Our work addressed the following elements of the Call for Proposals: (i) ???to improve the theoretical representation of aerosol processes studied in ASP laboratory or field studies???, (ii) ???to enhance the incorporation of aerosol process information into modules suitable for large-scale or global atmospheric models???, and (iii) ???provide systematic experimental validation of process model predictions ... using data from targeted laboratory and field experiments???. Achievements to the end of 2012 are described in four previous reports, and include: new models of densities and surface tensions of pure (single solute) and mixed aqueous solutions of typical aerosol composition under all atmospheric conditions (0 to 100% RH and T > 150 K); inclusion of these models into the widely used Extended Aerosol Inorganics model (E-AIM, http://www.aim.env.uea.ac.uk/aim/aim.php); the addition of vapor pressure calculators for organic compounds to the E-AIM website; the ability of include user-defined organic compounds and/or lumped surrogates in gas/aerosol partitioning calculations; the development of new equations to represent the properties of soluble aerosols over the entire concentration range (using methods based upon adsorption isotherms, and derived using statistical mechanics), including systems at close to zero RH. These results are described in publications 1-6 at the end of this report, and on the ???News??? page of the E-AIM website (http://www.aim.env.uea.ac.uk/aim/info/news.html). During 2012 and 2013 we have collaborated in a combined observation and lab-based study of the water uptake of the organic component of atmospheric aerosols (PI Gannet Hallar, of the Desert Research Institute). The aerosol samples were analyzed using several complementary techniques (GC/MS, FT-ICR MS, and ion chromatography) to produce a very complete organic ???speciation??? including both polar and non-polar compounds. Hygroscopic growth factors of the samples were measured, and we have just completed comparisons of the data with our process model predictions based upon the inorganic and organic composition of the samples.