Centrifugal contactor operations for UREX process flowsheet. An update

Pereira, Candido¹  Vandegrift, George F.¹ 

[1]Argonne National Lab. (ANL), Argonne, IL (United States)

关键词: COMPARATIVE EVALUATIONS;    SOLVENT EXTRACTION;    SPENT FUELS;    URANIUM;    REPROCESSING;    IODINE;    TECHNETIUM;    EXTRACTION APPARATUSES;    NITRIC ACID;    DIAGRAMS;    LENGTH;    DIMENSIONS;    SIZE;    OPTIMIZATION;    DESIGN;    FLOORS;    SPACE;   

DOI  :  10.2172/1226919
RP-ID  :  ANL/CSE--14/21
PID  :  OSTI ID: 1226919
Others  :  Other: 106663
Others  :  TRN: US1500900

学科分类：核能源与工程

美国|英语

来源: SciTech Connect

【 摘 要 】

The uranium extraction (UREX) process separates uranium, technetium, and a fraction of the iodine from the other components of the irradiated fuel in nitric acid solution. In May 2012, the time, material, and footprint requirements for treatment of 260 L batches of a solution containing 130 g-U/L were evaluated for two commercial annular centrifugal contactors from CINC Industries. These calculated values were based on the expected volume and concentration of fuel arising from treatment of a single target solution vessel (TSV). The general conclusions of that report were that a CINC V-2 contactor would occupy a footprint of 3.2 m ² (0.25 m x 15 m) if each stage required twice the nominal footprint of an individual stage, and approximately 1,131 minutes or nearly 19 hours is required to process all of the feed solution. A CINC V-5 would require approximately 9.9 m ² (0.4 m x 25 m) of floor space but would require only 182 minutes or ~ 3 hours to process the spent target solution. Subsequent comparison with the Modular Caustic Side Solvent Extraction Unit (MCU) at Savannah River Site (SRS) in October 2013 suggested that a more compact arrangement is feasible, and the linear dimension for the CINC V-5 may be reduced to about 8 m; a comparable reduction for the CINC V-2 yields a length of 5 m. That report also described an intermediate-scale (10 cm) contactor design developed by Argonne in the early 1980s that would better align with the SHINE operations as they stood in May 2012. In this report, we revisit the previous evaluation of contactor operations after discussions with CINC Industries and analysis of the SHINE process flow diagrams for the cleanup of the TSV, which were not available at the time of the first assessment.