Two-step milling on the carbonyl iron particles and optimizing on the composite absorption

JOURNAL OF ALLOYS AND COMPOUNDS

卷:676

Article

Xu, Yonggang¹  Yuan, Liming¹  Wang, Xiaobing¹  Zhang, Deyuan² 

[1] Sci & Technol Electromagnet Scattering Lab, Shanghai 200438, Peoples R China

[2] Beihang Univ, Sch Mech Engn & Automat, Bion & Micro Nano Bio Mfg Technol Res Ctr, Beijing 100191, Peoples R China

关键词: Composite material;    Metals and alloys;    Mechanochemical;    Magnetic measurements;   

DOI  :  10.1016/j.jallcom.2016.03.192

来源: Elsevier

【 摘 要 】

The flaky carbonyl iron particles (CIPs) were prepared using a two-step milling process. The surface morphology was characterized by the scanning electron microscopy, the static magnetic property was evaluated on a vibrating sample magnetometer and X-ray diffraction (XRD) patterns were done to analyze the particle crystal grain structure. The complex permittivity and permeability were measured using a vector network analyzer in the frequency range of 2-18 GHz. Then Hermite interpolation based on the calculated scattering parameters of the tested composite was used to derive the permittivity and permeability of the composite with random volume content. The results showed that the saturation magnetization value of the flaky CIPs decreased as the CIPs was changed to the flakes by high and low speeding milling. The diffraction peaks of the single alpha-Fe existed in the XRD pattern of CIPs, and the characteristic peaks was broad and the intensity of the diffraction pattern was lower as the high-speeding milling time increased. The sample H2L20 had the largest particle size, the average diameter was 8.64 mu m, the thickness was 0.59 mu m according to the fitted aspect ratio 14.65. The derived permittivity and permeability using the Hermite interpolation was accurate compared with the tested result, the deviation was about 0.39 + j0.45 and 2.5 + j0.51. Finally, the genetic algorithm was used to optimize the thickness of the CIPs composite of a wide absorbing band of 8-18 GHz. The optimized reflection loss (RL) result showed that the absorbing composites with thickness 1.47 mm had an excellent absorbing property (RL < -10 dB) in 8-18 GHz. (C) 2016 Elsevier B.V. All rights reserved.

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