Size effects of ferroelectric and magnetoelectric properties of semi-ellipsoidal bismuth ferrite nanoparticles

JOURNAL OF ALLOYS AND COMPOUNDS

卷:714

Article

Khist, Victoria V.^1,2  Eliseev, Eugene A.³  Glinchuk, Maya D.³  Silibin, Maxim V.⁴  Karpinsky, Dmitry V.⁵  Morozovska, Anna N.⁶ 

[1] Natl Acad Sci Ukraine, Inst Magnetism, 36-b,Pr Akad Vernadskoho, UA-03142 Kiev, Ukraine

[2] Minist Educ & Sci Ukraine, 36-b,Pr Akad Vernadskoho, UA-03142 Kiev, Ukraine

[3] Natl Acad Sci Ukraine, Inst Problems Mat Sci, Krjijanovskogo Str 3, UA-03142 Kiev, Ukraine

[4] Natl Res Univ Elect Technol MIET, Sq Shokina Bldg 1, Moscow 124498, Russia

[5] Sci Pract Mat Res Ctr NAS Belarus, P Brovka Str 19, Minsk 220072, BELARUS

[6] Natl Acad Sci Ukraine, Inst Phys, 46,Pr Nauky, UA-03028 Kiev, Ukraine

关键词: Multiferroics;    Structural antiferrodistortion;    Antiferromagnetic order;    Nanoparticle;    Semi-ellipsoidal;    Nano-islands;   

DOI  :  10.1016/j.jallcom.2017.04.201

来源: Elsevier

【 摘 要 】

Bismuth ferrite (BiFeO3) is one of the most promising multiferroics with a sufficiently high ferroelectric (FE) and antiferromagnetic (AFM) transition temperatures, and magnetoelectric (ME) coupling coefficient at room temperature. So BiFeO3 is highly sensitive to the impact of cross-influence of applied electric and magnetic fields. According to the urgent demands of nanotechnology to miniaturize the working elements for ultra-high density data storage in advanced nonvolatile memory cells, it is very important to reduce the sizes of multiferroic nanoparticles in the self-assembled arrays without serious deterioration of their properties. This work studies size effects of the phase diagrams, FE and ME properties of semi-ellipsoidal BiFeO3 nanoparticles clamped to a rigid conductive substrate. The spatial distribution of the spontaneous polarization vector inside the nanoparticles, phase diagrams and para-magnetoelectric (PME) coefficient were calculated in the framework of the modified Landau-Ginzburg-Devonshire (LGD) approach. Analytical expressions were derived for the dependences of the FE transition temperature, average polarization, linear dielectric susceptibility and PME coefficient on the particle sizes for a general case of a semi-ellipsoidal nanoparticles with different semi-axes a, b and height c. The analyses of the obtained results leads to the conclusion that the size effect of the phase diagrams, spontaneous polarization and PME coefficient is rather sensitive to the aspect ratio of particle sizes in the polarization direction, and less sensitive to the absolute values of the sizes. (C) 2017 Elsevier B.V. All rights reserved.

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