Evolution of Fe environments in mechanically alloyed Fe-Nb-(B) compositions

JOURNAL OF ALLOYS AND COMPOUNDS

卷:615

Article; Proceedings Paper

Blazquez, J. S.¹  Ipus, J. J.¹  Conde, C. F.¹  Conde, A.¹ 

[1] Univ Seville, ICMSE CSIC, Dept Fis Mat Condensada, E-41080 Seville, Spain

关键词: Mechanical alloying;    Mossbauer spectroscopy;    Nanocrystalline alloys;   

DOI  :  10.1016/j.jallcom.2013.11.118

来源: Elsevier

【 摘 要 】

Nanocrystalline alloys of nominal composition Fe85Nb5B10 were produced by mechanical alloying from a mixture of elemental powders. Two commercial boron structures were used: amorphous and crystalline. In addition, a third composition Fe94.4Nb5.6 was prepared for comparison. X-ray diffraction and Mossbauer spectroscopy were used to describe the evolution of the microstructure and Fe environments as a function of the milling time. Whereas Nb is rapidly incorporated into the nanocrystalline matrix, boron inclusions remain even after long milling times. The presence of boron is found to enhance the comminuting of crystallites. (C) 2013 Elsevier B.V. All rights reserved.

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