Structural investigation of mechanically activated ZnO powder

JOURNAL OF ALLOYS AND COMPOUNDS

卷:648

Article

Peles, A.¹  Pavlovic, V. P.²  Filipovic, S.¹  Obradovic, N.¹  Mancic, L.¹  Krstic, J.³  Mitric, M.⁴  Vlahovic, B.⁵  Rasic, G.⁵  Kosanovic, D.¹  Pavlovic, V. B.¹ 

[1] Inst Tech Sci SASA, Belgrade 11000, Serbia

[2] Univ Belgrade, Fac Mech Engn, Belgrade 11000, Serbia

[3] Univ Belgrade, Inst Chem Technol & Met, Belgrade 11000, Serbia

[4] Inst Nucl Sci Vinca, Solid State Phys Lab, Belgrade 11001, Serbia

[5] N Carolina Cent Univ, Durham, NC 27707 USA

关键词: Mechanical activation;    N-2 physisorption;    XRD;    XPS;    SEM;    TEM;    Raman spectroscopy;    ZnO;   

DOI  :  10.1016/j.jallcom.2015.06.247

来源: Elsevier

【 摘 要 】

Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation. (C) 2015 Published by Elsevier B.V.

【 授权许可】

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