Anion effects on the interfacial alloying in successively electrodeposited Cu and Au ultrathin films

JOURNAL OF ALLOYS AND COMPOUNDS

卷:762

Article

Ambrozik, Stephen¹  Dimitrov, Nikolay¹ 

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

关键词: Nanoporous Au;    Cu-Au alloys;    De-alloying;    Ultrathin films;    Catalysts;   

DOI  :  10.1016/j.jallcom.2018.05.229

来源: Elsevier

【 摘 要 】

The alloying between successively deposited ultrathin (similar to 10 nm) films of Cu and Au is explored. Au is deposited on Cu films via conventional overpotential deposition (OPD) and mediated methods in chloride containing electrolyte (CCE), and via OPD in thiosulfate containing electrolyte (TCE). It is determined via electrochemical means that Au deposition on Cu results in alloy formation in all cases, justified by the exothermic enthalpy of Au-Cu mixing. Deposition in TCE results in more homogeneous, multi-phase alloy formation evidenced by positively shifted Cu stripping behavior. This is attributed to the thiosulfate adsorption limiting Au and Cu mobility thus yielding the formation of continuous and smaller-grained over-layers. In contrast, the enhanced mobility of Au ad-atoms in CCE facilitates 3D growth, evidenced by SEM to yield larger grains with well-defined facets and limited alloying. It was shown via XPS that alloys deposited from TCE exhibit a concentration gradient from the center of films to the exteriors and that S is present in the as-deposited films. In addition, following Cu stripping, it is shown that a variety of nanoporous and S-free Au structures can be formed with variable ligament and facet size, ultimately providing opportunity for catalyst design on the nanoscale. (C) 2018 Elsevier B.V. All rights reserved.

【 授权许可】

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