Treatment of sugarcane vinasse by combination of coagulation/flocculation and Fenton's oxidation

JOURNAL OF ENVIRONMENTAL MANAGEMENT

卷:181

Article

Guerreiro, Ligia F.¹  Rodrigues, Carmen S. D.¹  Duda, Rose M.²  de Oliveira, Roberto A.³  Boaventura, Rui A. R.⁴  Madeira, Luis M.¹ 

[1] Univ Porto, Fac Engn, Dept Engn Quim, LEPABE, P-4200465 Oporto, Portugal

[2] Fac Tecnol Jaboticabal, Av Eduardo Zambianchi 31, BR-14883130 Jaboticabal, SP, Brazil

[3] Univ Estadual Paulista, UNESP, Fac Ciencias Agr & Vet, Dept Engn Rural,Lab Saneamento Ambiental, Av Prof Paulo Donato Castallene,Km 5, BR-14884900 Jaboticabal, SP, Brazil

[4] Univ Porto, LSRE Lab Proc Separacao & Reacao, Lab Assoc LSRE LCM, Dept Engn Quim,Fac Engn, P-4200465 Oporto, Portugal

关键词: Sugarcane vinasse;    Anaerobic effluent biodegradability;    Toxicity;    Coagulation/flocculation;    Fenton's reaction;    Economic analysis;   

DOI  :  10.1016/j.jenvman.2016.06.027

来源: Elsevier

【 摘 要 】

The efficiency of individual and integrated processes applied to organic matter reduction and biodegradability improvement of a biodigested sugarcane vinasse wastewater was assessed. Strategies considered were Fenton's oxidation (Strategy 1), coagulation/flocculation (Strategy 2) and the combination of both processes (coagulation/flocculation followed by Fenton's reaction) - Strategy 3. It was found that Fenton's oxidation per se allowed reducing the organic matter, increasing the wastewater biodegradability and a non-toxic effluent was generated; however the cost of treatment was very high (86.6 R$/m(3) 21.2(sic)/m(3)). Under optimized conditions, coagulation/flocculation provided a slight increase in effluent's biodegradability, toxicity towards Vibrio fischeri was also eliminated and moderate removals of total organic carbon - TOC - (30.5%), biological oxygen demand - BOD5 - (27.9%) and chemical oxygen demand - COD - (43.6%) were achieved; however, the operating costs are much smaller. The use of dissolved iron resulting from coagulation/flocculation (270 mg/L) as catalyst in the second stage Fenton's oxidation was shown to be an innovative and economically attractive strategy. Under optimal conditions overall removals of 51.6% for TOC, 45.7% for BOD5 and 69.2% for COD were achieved, and a biodegradable (BOD5:COD ratio = 0.54) and non-toxic effluent was obtained. In order to increase the efficiency of the process but using less hydrogen peroxide, the Fenton's oxidation was performed by gradually adding the oxidant. This procedure allowed to obtain the highest organic matter removal efficiency (as compared with the addition of all hydrogen peroxide at the beginning of the reaction). This way it was possible to minimize the reagent consumption and, consequently, reduce the treatment cost. (C) 2016 Elsevier Ltd. All rights reserved.

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