Thermally stable surfactant-free ceria nanocubes in silica aerogel

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:583

Article

Caddeo, Francesco¹  Casu, Alberto²  Loche, Danilo¹  Morgan, Lucy M.¹  Mountjoy, Gavin¹  O'Regan, Colm²  Casula, Maria F.³  Hayama, Shusaku⁴  Corrias, Anna¹  Falqui, Andrea² 

[1] Univ Kent, Sch Phys Sci, Ingram Bldg, Canterbury CT2 7NH, Kent, England

[2] King Abdullah Univ Sci & Technol KAUST, Biol & Environm Sci & Engn BESE Div, Nabla Lab, Thuwal 239556900, Saudi Arabia

[3] Univ Cagliari, Dept Mech Chem & Mat Engn, Via Marengo 2, I-09123 Cagliari, Italy

[4] Diamond Light Source, Harwell Sci & Innovat Campus, Didcot OX11 0DE, Oxon, England

关键词: Ceria;    Nanocubes;    Capping agents;    SiO2 Aerogel;   

DOI  :  10.1016/j.jcis.2020.09.044

来源: Elsevier

【 摘 要 】

Surfactant-mediated chemical routes allow one to synthesize highly engineered shape- and size-controlled nanocrystals. However, the occurrence of capping agents on the surface of the nanocrystals is undesirable for selected applications. Here, a novel approach to the production of shape-controlled nanocrystals which exhibit high thermal stability is demonstrated. Ceria nanocubes obtained by surfactant-mediated synthesis are embedded inside a highly porous silica aerogel and thermally treated to remove the capping agent. Powder X-ray Diffraction and Scanning Transmission Electron Microscopy show the homogeneous dispersion of the nanocubes within the aerogel matrix. Remarkably, both the size and the shape of the ceria nanocubes are retained not only throughout the aerogel syntheses but also upon thermal treatments up to 900 degrees C, while avoiding their agglomeration. The reactivity of ceria is measured by in situ High-Energy Resolution Fluorescence Detected - X-ray Absorption Near Edge Spectroscopy at the Ce L-3 edge, and shows the reversibility of redox cycles of ceria nanocubes when they are embedded in the aerogel. This demonstrates that the enhanced reactivity due to their prominent {100} crystal facets is preserved. In contrast, unsupported ceria nanocubes begin to agglomerate as soon as the capping agent decomposes, leading to a degradation of their reactivity already at 275 degrees C. (C) 2020 The Authors. Published by Elsevier Inc.

【 授权许可】

Free