Directed self-assembly of silica nanoparticles in ionic liquid-spun cellulose fibers

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:553

Article

Trojer, Markus Andersson¹  Olsson, Carina¹  Bengtsson, Jenny²  Hedlund, Arthur²  Bordes, Romain³ 

[1] RISE IVF, Biobased Fibres, Dept Mat, S-43153 Molndal, Sweden

[2] Chalmers Univ Technol, Dept Chem & Chem Engn, Forest Prod & Chem Engn, S-41296 Gothenburg, Sweden

[3] Chalmers Univ Technol, Appl Surface Chem, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden

关键词: Wet-spinning;    Biocomposites;    Mechanical properties;    Surface topography;    Plasma-enhanced chemical vapor deposition;   

DOI  :  10.1016/j.jcis.2019.05.084

来源: Elsevier

【 摘 要 】

The application range of man-made cellulosic fibers is limited by the absence of cost- and manufacturing efficient strategies for anisotropic hierarchical functionalization. Overcoming these bottlenecks is therefore pivotal in the pursuit of a future bio-based economy. Here, we demonstrate that colloidal silica nanoparticles (NPs), which are cheap, biocompatible and easy to chemically modify, enable the control of the cross-sectional morphology and surface topography of ionic liquid-spun cellulose fibers. These properties are tailored by the silica NPs' surface chemistry and their entry point during the wet spinning process (dope solution (SiO2)-Si-D or coagulation bath (SiO2)-Si-C). For (SiO2)-Si-C-modified fibers, the coagulation mitigator dimethylsulphoxide allows for controlling the surface topography and the amalgamation of the silica NPs into the fiber matrix. For dope-modified fibers, we hypothesize that cellulose chains act as seeds for directed silica NP self-assembly. This results for (SiO2)-Si-D in discrete micron-sized rods, homogeneously distributed throughout the fiber and for glycidoxy-surface modified (SiO2)-Si-D@GLYEO in nano-sized surface aggregates and a cross-sectional core-shell fiber morphology. Furthermore, the dope-modified fibers display outstanding strength and toughness, which are both characteristic features of biological biocomposites. (C) 2019 Published by Elsevier Inc.

【 授权许可】

Free