Self-assembly in dilute mixtures of non-ionic and anionic surfactants and rhamnolipd biosurfactants

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:487

Article

Liley, J. R.^1,6  Penfold, J.^1,2  Thomas, R. K.¹  Tucker, I. M.³  Petkov, J. T.^3,7  Stevenson, P. S.³  Banat, I. M.⁴  Marchant, R.⁴  Rudden, M.⁴  Terry, A.²  Grillo, I.⁵ 

[1] Univ Oxford, Phys & Theoret Chem Lab, South Parks Rd, Oxford, England

[2] ISIS, STFC, Rutherford Appleton Lab, Didcot, Oxon, England

[3] Unilever Res & Dev Lab Port Sunlight, Quarry Rd East, Wirral, Merseyside, England

[4] Univ Ulster, Sch Biomed Sci, Coleraine, Londonderry, North Ireland

[5] Inst Lane Langevin, 71 Ave Martyrs,CS 20156, F-38042 Grenoble 09, France

[6] LGC, Queens Rd, Teddington TW11 0LY, Middx, England

[7] Lonza UK, GB Blackley, Manchester M9 8ES, Lancs, England

关键词: Mixed surfactants;    Biosurfactants;    Self-assembly;    Mixed micelles;    Small angle neutron scattering;   

DOI  :  10.1016/j.jcis.2016.10.071

来源: Elsevier

【 摘 要 】

The self-assembly of dilute aqueous solutions of a ternary surfactant mixture and rhamnolipid biosurfactant/surfactant mixtures has been studied by small angle neutron scattering. In the ternary surfactant mixture of octaethylene glycol monododecyl ether, C12E8, sodium dodecyl 6-benzene sulfonate, LAS, and sodium dioxyethylene monododecyl sulfate, SLES, small globular interacting micelles are observed over the entire composition and concentration range studied. The modelling of the scattering data strongly supports the assumption that the micelle compositions are close to the solution compositions. In the 5-component rhamnolipid/surfactant mixture of the mono-rhamnose, R1, di-rhamnose, R2, rhamnolipids with C12E8/LAS/SLES, globular micelles are observed over much of the concentration and composition range studied. However, for solutions relatively rich in rhamnolipid and LAS, lamellar/micellar coexistence is observed. The transition from globular to more planar structures arises from a synergistic packing in the 5 component mixture. It is not observed in the individual components nor in the ternary C12E8/LAS/SLES mixture at these relatively low concentrations. The results provide an insight into how synergistic packing effects can occur in the solution self-assembly of complex multi-component surfactant mixtures, and give rise to an unexpected evolution in the phase behaviour. (C) 2016 Elsevier Inc. All rights reserved.

【 授权许可】

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