Synthesis of nanometer-sized fayalite and magnesium-iron(II) mixture olivines

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:515

Article

Qafoku, Odeta¹  Ilton, Eugene S.¹  Bowden, Mark E.²  Kovarik, Libor²  Zhang, Xin¹  Kukkadapu, Ravi K.²  Engelhard, Mark H.²  Thompson, Christopher J.³  Schaef, Herbert T.¹  McGrail, Bernard Peter³  Rosso, Kevin M.¹  Loring, John S.¹ 

[1] Pacific Northwest Natl Lab, Phys & Computat Sci Directorate, Richland, WA 99352 USA

[2] Pacific Northwest Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA

[3] Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA

关键词: Olivine;    Orthosilicate;    Forsterite;    Fayalite;    Nanomaterial;    Synthesis;   

DOI  :  10.1016/j.jcis.2018.01.036

来源: Elsevier

【 摘 要 】

Olivines are divalent orthosilicates with important geologic, biological, and industrial significance and are typically comprised of mixtures of Mg2+ and Fe2+ ranging from forsterite (Mg2SiO4) to fayalite (Fe2SiO4). Investigating the role of Fe(II) in olivine reactivity requires the ability to synthesize olivines that are nanometer-sized, have different percentages of Mg2+ and Fe2+, and have good bulk and surface purity. This article demonstrates a new method for synthesizing nanosized fayalite and Mg-Fe mixture olivines. First, carbonaceous precursors are generated from sucrose, PVA, colloidal silica, Mg2+, and Fe3+. Second, these precursors are calcined in air to burn carbon and create mixtures of Fe(III)-oxides, forsterite, and SiO2. Finally, calcination in reducing CO-CO2 gas buffer leads to Fe(II)-rich olivines. XRD, Mossbauer, and IR analyses verify good bulk purity and composition. XPS indicates that surface iron is in its reduced Fe(II) form, and surface Si is consistent with olivine. SEM shows particle sizes predominately between 50 and 450 nm, and BET surface areas are 2.8-4.2 m(2)/g. STEM HAADF analysis demonstrates even distributions of Mg and Fe among the available M1 and M2 sites of the olivine crystals. These nanosized Fe(II)-rich olivines are suitable for laboratory studies with in situ probes that require mineral samples with high reactivity at short timescales. (C) 2018 Elsevier Inc. All rights reserved.

【 授权许可】

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