Laponite/poly(2-methyl-2-oxazoline) hydrogels: Interplay between local structure and rheological behaviour

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:582

Article

Le Coeur, C.^1,2  Lorthioir, C.³  Feoktystov, A.⁴  Wu, B.⁴  Volet, G.^1,5  Amiel, C.¹ 

[1] Univ Paris Est Creteil, CNRS, Inst Chim & Mat Paris Est, 2 Rue Henri Dunant, F-94320 Thiais, France

[2] Univ Paris Saclay, CEA Saclay, Lab Leon Brillouin, CEA,CNRS,UMR 12, F-91191 Gif Sur Yvette, France

[3] Sorbonne Univ, Lab Chim Matiere Condensee Paris, CNRS, Coll France, 4 Pl Jussieu, F-75005 Paris, France

[4] Forschungszentrum Julich, Julich Ctr Neutron Sci JCNS, Heinz Maier Leibnitz Zentrum MLZ, Lichtenbergstr 1, D-85748 Garching, Germany

[5] Univ Evry Val dEssonne, Rue Pere Jarlan, F-91025 Evry, France

关键词: Poly(2-Methyl-2-Oxazoline);    Clays;    Hydrogels;    Nanocomposites;    Adsorption;    Sans;   

DOI  :  10.1016/j.jcis.2020.07.068

来源: Elsevier

【 摘 要 】

Hypothesis: Dispersions of Laponite in water may form gels, the rheological properties of which being possibly tuned by the addition of polymer chains. Laponite-based hydrogels with poly(ethylene oxide) (PEO) were the most widely investigated systems and the PEO chains were then found to reduce the elastic modulus. Experiments: Here, hydrogels based on Laponite and poly(2-methyl-2-oxazoline) (POXA) were considered. The adsorption behavior and the local structures within these nanocomposite gels were investigated by small-angle neutron scattering and NMR. The same materials were macroscopically characterized using rheology. Findings: An original evolution of the storagemodulus G' with the POXA concentration is evidenced compared to Laponite/PEO hydrogels. At low POXA concentrations, a continuous reduction of G' is observed upon increasing the polymer content, as with PEO, due to the screening of electrostatic interactions between the clay platelets. However, above a critical value of the POXA concentration, G' increases with the polymer content. This difference with PEO-based hydrogels is correlated to the stronger affinity of POXA chains for the clay surfaces, which results in the reduction of the inhomogeneities for the Laponite disks within the gels. Steric repulsions would then counterbalance the effect of electrostatic repulsions and lead to the strengthening of the POXA-based hydrogels. (C) 2020 Elsevier Inc. All rights reserved.

【 授权许可】

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