Mechanical behavior of biopolymer composite coatings on plastic films by depth-sensing indentation - A nanoscale study

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:512

Article

Rovera, Cesare¹  Cozzolino, Carlo A.¹  Ghaani, Masoud¹  Morrone, Davide^2,3  Olsson, Richard T.⁴  Farris, Stefano^1,5 

[1] Univ Milan, Environm & Nutr Sci Packaging Div, Dept Food, DeFENS, Via Celoria 2, I-20133 Milan, Italy

[2] R&D Srl Tecnol Mat, Galleria Gandhi 2, I-20017 Mazzo Di Rho, Italy

[3] Nanovea Inc, 6 Morgan,Ste 156, Irvine, CA 92618 USA

[4] KTH Royal Inst Technol, Sch Chem Sci & Engn, Dept Fibre & Polymer Technol, Teknikringen 56, SE-10044 Stockholm, Sweden

[5] Univ Milan, Local Unit, INSTM, Natl Consortium Mat Sci & Technol, Via Celoria 2, I-20133 Milan, Italy

关键词: Aggregation;    Biopolymer;    Cellulose nanocrystals (CNCs);    Coating;    Interface;    Nanoindentation;    Nanocomposite;    Phase separation;    Pullulan;    Surface;   

DOI  :  10.1016/j.jcis.2017.10.108

来源: Elsevier

【 摘 要 】

Fundamental physical behaviors of materials at the nanoscale level are crucial when local aspects govern the macroscale performance of nanocomposites, e.g., interface and surface phenomena. Because of the increasing interest in biopolymer nanocomposite coatings for many different applications (e.g., optical devices, displays/screens, and packaging), this work investigates the potential of nanoindentation as a method for clarifying the interplay between distinct phases (i.e., organic and inorganic) at local level in thin biopolymer films loaded with nanoparticles. The nanomechanical features of pullulan nanocomposite coatings laid on polyethylene terephthalate (PET) were quantified in terms of elastic modulus (E), hardness (H), and creep (C) through an instrumented indentation test composed of a loading-holding unloading cycle. Colloidal silica (CS) and cellulose nanocrystals (CNCs) were used as spherical and rodlike nanoparticles, respectively. An overall reinforcing effect was shown for all nanocomposite coatings over the pristine (unfilled) pullulan coating. A size effect was also disclosed for the CS-loaded surfaces, with the highest E value recorded for the largest particles (8.19 +/- 0.35 GPa) and the highest H value belonging to the smallest ones (395.41 +/- 25.22 MPa). Comparing CS and CNCs, the addition of spherical nanoparticles had a greater effect on the surface hardness than cellulose nanowhiskers (353.50 +/- 83.52 MPa and 321.36 +/- 43.26 MPa, respectively). As for the elastic modulus, the addition of CS did not provide any improvement over both the bare and CNC-loaded pullulan coatings, whereas the coating including CNCs exhibited higher E values (p < .05). Finally, CS-loaded pullulan coatings were the best performing in terms of C properties, with an average indentation depth of 16.5 +/- 1.85 nm under a load of similar to 190 mu N. These results are discussed in terms of local distribution gradients, surface chemistry of nanoparticles, and how nanoparticle aggregation occurred in the dry nanocomposite coatings. (C) 2017 Elsevier Inc. All rights reserved.

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