Adsorption of polycyclic aromatic hydrocarbons from aqueous solutions by modified periodic mesoporous organosilica

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:357

Article

Vidal, Carla B.¹  Barros, Allen L.²  Moura, Cicero P.²  de Lima, Ari C. A.¹  Dias, Francisco S.³  Vasconcellos, Luiz. C. G.³  Fechine, Pierre B. A.²  Nascimento, Ronaldo F.² 

[1] Univ Fed Ceara, Dept Hydraul & Environm Engn, BR-60451970 Fortaleza, Ceara, Brazil

[2] Univ Fed Ceara, Dept Analyt Chem & Phys Chem, BR-60451970 Fortaleza, Ceara, Brazil

[3] Univ Fed Ceara, Dept Organ & Inorgan Chem, BR-60451970 Fortaleza, Ceara, Brazil

关键词: PAHs;    Adsorption;    PMO;    Adsorption models;   

DOI  :  10.1016/j.jcis.2011.02.013

来源: Elsevier

【 摘 要 】

A novel procedure was developed for the synthesis of a periodic mesoporous organosilica (PMO), which was used to remove polycyclic aromatic hydrocarbons (PAHs) from aqueous solutions. Adsorption equilibrium isotherms and adsorption kinetics experiments were carried out in solutions of PAHs (2-60 mg L-1), using the PMO as adsorbent. Adsorption models were used to predict the mechanisms involved. The adsorption kinetics data best fitted the pseudo-first-order kinetic model for naphthalene, and to the pseudo-second-order model for fluorene, fluoranthene, pyrene, and acenaphtene. The intraparticle model was also tested and pointed to the occurrence of such processes in all cases. The isotherm models which best represented the data obtained were the Freundlich model for fluoranthene, pyrene, and fluorene, the Temkin model for naphthalene, and the Redlich-Peterson model for acenaphtene. PAHs showed similar behavior regarding kinetics after 24 h of contact between adsorbent and PAHs. FTIR, XRD, BET, and SEM techniques were used for the characterization of the adsorbent material. (C) 2011 Elsevier Inc. All rights reserved.

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