Carbon nanotube/Prussian blue thin films as cathodes for flexible, transparent and ITO-free potassium secondary battery

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:478

Article

Nossol, Edson^1,2  Souza, Victor H. R.¹  Zarbin, Aldo J. G.¹ 

[1] Fed Univ Parana UFPR, Dept Chem, CP 19083, BR-81531980 Curitiba, Parana, Brazil

[2] Univ Fed Uberlandia, Inst Quim, Ave Joao Naves Avila 2121, Uberlandia, MG, Brazil

关键词: Prussian blue;    Carbon nanostructures;    Thin films;    Flexible devices;    Ion-battery;    Nanocomposites;   

DOI  :  10.1016/j.jcis.2016.05.056

来源: Elsevier

【 摘 要 】

Thin films of either unpurified single-walled carbon nanotubes (SWCNT) or iron-filled multi-walled carbon nanotubes (MWCNT) were deposited through the liquid-liquid interfacial route over plastic substrates, yielding transparent, flexible and ITO-free electrodes. The iron species presented in both electrodes (inside of the MWCNT cavities or outside of the SWCNT bundles, related to the catalyst remaining of the growth process) were employed as reactant to the electrosynthesis of Prussian blue (PB), yielding carbon nanotubes/Prussian blue nanocomposite thin films, which were characterized by Raman spectroscopy, scanning electron microscopy, atomic force microscopy, cyclic voltammetry and galvanostatic charge/discharge measurements. The nanocomposite films were employed as cathodes for flexible, transparent and ITO-free potassium batteries, showing reversible charge/discharge behavior and specific capacitance of 8.3 mA h cm(-3) and 2.7 mA h cm(-3) for SWCNT/PB and MWCNT/PB, respectively. (C) 2016 Elsevier Inc. All rights reserved.

【 授权许可】

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