Bioelectrochemical recovery of Cu, Pb, Cd, and Zn from dilute solutions

JOURNAL OF HAZARDOUS MATERIALS

卷:235

Article

Modin, Oskar¹  Wang, Xiaofei¹  Wu, Xue¹  Rauch, Sebastien¹  Fedje, Karin Karlfeldt^1,2 

[1] Chalmers, Dept Civil & Environm Engn, Div Water Environm Technol, S-41296 Gothenburg, Sweden

[2] Renova AB, S-40122 Gothenburg, Sweden

关键词: Microbial electrolysis cell;    Metal recovery;    Ash leachate;    Electrowinning;    Municipal solid waste;   

DOI  :  10.1016/j.jhazmat.2012.07.058

来源: Elsevier

【 摘 要 】

In a microbial bioelectrochemical system (BES) living microorganisms catalyze the anodic oxidation of organic matter at a low anode potential. We used a BES with a biological anode to power the cathodic recovery of Cu, Pb, Cd, and Zn from a simulated municipal solid waste incineration ash leachate. By varying the control of the BES, the four metals could sequentially be recovered from a mixed solution by reduction on a titanium cathode. First, the cell voltage was controlled at zero, which allowed recovery of Cu from the solution without an electrical energy input. Second, the cathode potential was controlled at -0.51 V to recover Pb, which required an applied voltage of about 0.34 V. Third, the cathode potential was controlled at -0.66V to recover Cd, which required an applied voltage of 0.51 V. Finally, Zn was the only metal remaining in solution and was recovered by controlling the anode at +0.2 V to maximize the generated current. The study is the first to demonstrate that a BES can be used for cathodic recovery of metals from a mixed solution, which potentially could be used not only for ash leachates but also for e.g. metallurgical wastewaters and landfill leachates. (C) 2012 Elsevier B.V. All rights reserved.

【 授权许可】

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