The impact of alkali metal halide electron donor complexes in the photocatalytic degradation of pentachlorophenol

JOURNAL OF HAZARDOUS MATERIALS

卷:321

Article

Khuzwayo, Z.¹  Chirwa, E. M. N.¹ 

[1] Univ Pretoria, Water Utilisat Div, Dept Chem Engn, ZA-0002 Pretoria, South Africa

关键词: Alkali metals;    Electron donors;    Photocatalysis;    Polychlorinated phenol;    Oxidation;   

DOI  :  10.1016/j.jhazmat.2016.08.069

来源: Elsevier

【 摘 要 】

The performance of photocatalytic oxidation of chemical pollutants is subjected to the presence of anion complexes in natural waters. This study investigated the influence of alkali metal (Na+ (sodium), K+. (potassium)) halides (C1(-) (chloride), Br- (bromide), F- (fluoride)) as inorganic ion sources in the photocatalytic degradation of pentachlorophenol (PCP) in batch systems. It was found that the exclusive presence of halides in the absence of an electron acceptor adequately facilitated the photocatalyst process, below critical levels of anion populations, where beyond the critical point the process was significantly hindered. Below the determined critical point, the performance in some cases near matches that of the facilitation of the photocatalytic process by exclusive oxygen, acting as an electron scavenger. The coupling of halide ions and oxygenation presented significantly improved photo-oxidation of PCP, this was confirmed by the inclusion of formic acid as a comparative electron donor. The Langmuir-Hinshelwood kinetic expression was used to calculate the performance rate kinetics. The probable impact of the halide anions was discussed with regards to the process of electron hole pair recombination prevention. (C) 2016 Elsevier B.V. All rights reserved.

【 授权许可】

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