Application of an amphoteric polymer for leather pickling to obtain a less total dissolved solids residual process

JOURNAL OF CLEANER PRODUCTION

卷:139

Article

Jia, Lu¹  Ma, Jianzhong^1,2  Gao, Dangge¹  Lyu, Bin^1,2  Zhang, Jing³ 

[1] Shaanxi Univ Sci & Technol, Coll Resources & Environm, Xian 710021, Peoples R China

[2] Shaanxi Res Inst Agr Prod Proc Technol, Xian 710021, Shaanxi, Peoples R China

[3] Shaanxi Univ Sci & Technol, Coll Arts & Sci, Xian 710021, Peoples R China

关键词: Less TDS residual process;    Amphoteric polymer;    Low-salt pickling;    Less chrome tanning;    Environmental friendly;    Leather process;   

DOI  :  10.1016/j.jclepro.2016.08.097

来源: Elsevier

【 摘 要 】

A clean approach of less total dissolved solids residual process based on an amphoteric polymer has been attempted. Amphoteric polymer was added in the pickling as experimental process. The amount of common salt reduced from 8% to 2% and the amount of basic chrome sulfate was 4%. 8% common salt was added in pickling and 4% basic chrome sulfate was added in tanning as control. The tanning waste water, wet blue and crust leathers were analysed. The results showed that the amphoteric polymer resulted in increment of Cr2O3 content in leather by 10.8%, and the amphoteric polymer offered leather showed better chromium distribution and collagen fibers distribution properties than conventional leather. The mechanical properties, colour value and shrinkage temperature of the leather treated with amphoteric polymer were close to those of the conventional leather. What's more, the Cr2O3 content of experimental tanning waste reduced by 53.5%, and the reduction in Cl- content is 78.3%, and the total dissolved solids in the experimental waste reduced to 178.11 g/L. From the results obtained, it is suggested that without affecting the quality of the finished leather, the amphoteric polymer offered process could reduce the pollution of tanning waste, and promote the development of cleaner production. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

Free