The influence of relative humidity on double dielectric barrier discharge plasma for chlorobenzene removal

JOURNAL OF CLEANER PRODUCTION

卷:288

Article

Zhou, Wu^1,2  Ye, Zhiping¹  Nikiforov, Anton³  Chen, Jun⁴  Wang, Jiade¹  Zhao, Liang¹  Zhang, Xiuwen¹ 

[1] Zhejiang Univ Technol, Coll Environm, Hangzhou 310014, Peoples R China

[2] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310014, Peoples R China

[3] Univ Ghent, Fac Engn, Dept Appl Phys, Res Unit Plasma Technol, Sint Pietersnieuwstr 41, B-9000 Ghent, Belgium

[4] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Hangzhou 310021, Peoples R China

关键词: Double dielectric barrier discharge;    Relative humidity;    Active substance;    Chlorobenzene removal;    Removal pathway;   

DOI  :  10.1016/j.jclepro.2020.125502

来源: Elsevier

【 摘 要 】

The influence of relative humidity on the electrical characteristics, the generation of the active species and the chlorobenzene removal performance was studied. The results show that both the peak-to-peak current and the discharge power decreased with the increase of relative humidity under the same peak-to-peak voltage. A reduction of electron temperature was observed with the addition of water vapour, affecting the electron impact processes. It was observed that excited states of N-2 and O were affected by the water due to the quenching effect. A decrease of chlorobenzene removal efficiency was achieved from 81.7% to 70.7% as the increase of humidity. However, carbon balance analysis depicts the yields of CO2 in humid air were higher than that in dry air due to the help of radical OH, especially in RH = 40%, and highest energy efficiency with 4.4 g kW(-1) h(-1) was also achieved at RH = 40%. Chlorine balance indicates that the product HCl is more easily generated in the presence of H2O. A difference in the chlorobenzene degradation pathway was revealed. Fewer kinds of benzenoid byproducts were found in dry air, which was in agreement with the plasma diagnostics results. Radicals generated in humid air promoted the total oxidation process, resulting in fewer kinds of ring-open byproducts and higher CO2 yield. (C) 2020 Elsevier Ltd. All rights reserved.

【 授权许可】

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