Insights into the potential release of dissolved organic matter from different agro-forest waste-derived hydrochars: A pilot study

JOURNAL OF CLEANER PRODUCTION

卷:319

Article

Ji, Rongting¹  Su, Lianghu¹  Cheng, Hu^2,3,4  Wang, Yuan⁵  Min, Ju⁵  Chen, Mei¹  Li, Haidong¹  Chen, Sujuan¹  Wang, Saier¹  Yu, Guo¹  Zhang, Longjiang¹  Han, Jiangang^2,4 

[1] Minist Ecol & Environm Peoples Republ China, Nanjing Inst Environm Sci, Nanjing 210042, Peoples R China

[2] Nanjing Forestry Univ, Coll Biol & Environm, Coinnovat Ctr Sustainable Forestry Southern China, Nanjing 210037, Peoples R China

[3] Beijing Construct Engn Environm Remediat Co Ltd, Natl Engn Lab Site Remediat Technol, Beijing 100015, Peoples R China

[4] Natl Positioning Observat Stn Hung Tse Lake Wetla, Huaian 223100, Peoples R China

[5] Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, Nanjing 210008, Peoples R China

关键词: Agro-forest waste;    Dissolved organic matter;    Excitation-emission matrix;    Hydrochar;    Parallel factor analysis;    UV-Vissible spectroscopy;   

DOI  :  10.1016/j.jclepro.2021.128676

来源: Elsevier

【 摘 要 】

Hydrochar derived from biowaste has recently attracted widespread interest for high-performance environmental applications. However, the potential release behaviors of dissolved organic matter from hydrochar (HDOM) in various environments are still unknown. In this study, three agro-forest waste-derived hydrochars were prepared, and the element composition, pore structure, thermal recalcitrance, functional groups and surface properties were characterized. Four extractants and two extraction temperatures were applied to simulate the possible environments. UV-visible spectroscopy and excitation-emission matrix spectra with parallel factor analysis were applied to evaluate the chemical properties of HDOM. The results showed that large quantities of HDOM could be leached, and the concentration of dissolved organic carbon ranged from 32.62 to 404.81 g kg(-1). Fulvic acid-like substances (34.01-60.38%), humic acid-like substances (12.53-37.31%) and protein-like substances (13.46-45.68%) were identified in HDOM. Alkaline and high-temperature conditions enhanced the release of HDOM with high aromaticity and hydrophobicity as well as a high molecular weight. Combined with principal component analysis, the order of the main influencing factors on the specific chemical properties of HDOM was extractant > feedstock > temperature. These findings confirmed that released HDOM would result in significant influences on soil remediation, carbon sequestration, wastewater treatment, and soil fertility improvement during the application of hydrochar. The environmental behavior of HDOM needs to be further investigated in the future.

【 授权许可】

Free