Linking the SO2 emission of cement plants to the sulfur characteristics of their limestones: A study of 80 NSP cement lines in China

JOURNAL OF CLEANER PRODUCTION

卷:220

Article

Zhang, Tongsheng^1,2  Wu, Chang¹  Li, Bin¹  Wang, Jiawei³  Ravat, Rasheeda³  Chen, Xinzhi⁴  Wei, Jiangxiong¹  Yu, Qijun¹ 

[1] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China

[2] UCL, Dept Civil Environm & Geomat Engn, London WC1E 6BT, England

[3] Aston Univ, Sch Engn & Appl Sci, Birmingham B4 7ET, W Midlands, England

[4] Guangdong Wanyin Technol Dev Co Ltd, Guangzhou 510075, Guangdong, Peoples R China

关键词: SO2 emission;    Sulfur characteristics;    Limestone;    NSP cement line;    Pyrite;   

DOI  :  10.1016/j.jclepro.2019.02.133

来源: Elsevier

【 摘 要 】

In a properly operated new suspension preheater (NSP) cement line, the SO2 emission is mainly originated from sulfides in the raw meal, and limestone, occupying about 85% wt. of the raw meal, is the dominant sulfur source. However, the sulfur characteristics of limestones and then their influences on the SO2 emission have not been clarified yet. In the present study, 80 NSP cement lines with SO2 emission >200 mg/Nm(3) were recorded, the sulfur content and species as well as pyrite morphology of limestones were analyzed and then correlated to their resulting SO2 emission. The results show that the SO2 emission of stack gas increases linearly with the SO3 content of limestone used, and sulfates lead to a 50% reduction in SO2 emission relative to sulfides. Compared with average SO2 emission, euhedral pyrite leads to a slightly higher SO2 emission, whereas metasomatic pyrite results in a lower SO2 emission, which can be attributed to the effects of accompanying elements (Ti, F, K, and Al etc.) on the desulfurization reaction and clinkerization in the whole NSP cement line. The relationships proposed can be used to predict the SO2 emission based on the sulfur characteristics of limestone and to rationally utilize high-sulfur limestone in cement industry. Crown Copyright (C) 2019 Published by Elsevier Ltd. All rights reserved.

【 授权许可】

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