The use of hydrogen to separate and recycle neodymium-iron-boron-type magnets from electronic waste

JOURNAL OF CLEANER PRODUCTION

卷:104

Article

Walton, A.¹  Yi, Han¹  Rowson, N. A.²  Speight, J. D.¹  Mann, V. S. J.¹  Sheridan, R. S.¹  Bradshaw, A.¹  Harris, I. R.¹  Williams, A. J.¹ 

[1] Univ Birmingham, Sch Met & Mat, Birmingham B15 2TT, W Midlands, England

[2] Univ Birmingham, Sch Chem Engn, Birmingham B15 2TT, W Midlands, England

关键词: Hydrogen;    Magnets;    NdFeB;    Recycle;    Rare-earth;   

DOI  :  10.1016/j.jclepro.2015.05.033

来源: Elsevier

【 摘 要 】

The rare earth metals have been identified by the European Union and the United States as being at greatest supply risk of all the materials for clean energy technologies. Of particular concern are neodymium and dysprosium, both of which are employed in neodymium iron boron based magnets. Recycling of magnets based on these materials and contained within obsolete electronic equipment, could provide an additional and secure supply. In the present work, hydrogen has been employed as a processing agent to decrepitate sintered neodymium iron boron based magnets contained within hard disk drives into a demagnetised, hydrogenated powder. This powder was then extracted mechanically from the devices with an extraction efficiency of 90 +/- 5% and processed further using a combination of sieves and ball bearings, to produce a powder containing <330 parts per million of nickel contamination. It is then possible for the extracted powder to be re-processed in a number of ways, namely, directly by blending and re-sintering to form fully dense magnets, by Hydrogenation, Disproportionation, Desorption, Recombination processing to produce an anisotropic coercive powder suitable for bonded magnets, by re-melting; or by chemical extraction of the rare earth elements from the alloy. For example, it was shown that, by the re-sintering route, it was possible to recover >90% of the magnetic properties of the starting material with significantly less energy than that employed in primary magnet production. The particular route used will depend upon the magnetic properties required, the level of contamination of the extracted material and the compositional variation of the feedstock. The various possibilities have been summarised in a flow diagram. (C) 2015 The Authors. Published by Elsevier Ltd.

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