Optimizing the process efficiency of atomic layer deposition of alumina for its sustainability improvement: a combined experimental and modeling study

JOURNAL OF CLEANER PRODUCTION

卷:133

Article

Xie, Yuanyuan¹  Pan, Dongqing¹  Ma, Lulu¹  Yuan, Chris¹ 

[1] Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53211 USA

关键词: Atomic layer deposition;    Optimization;    Alumina film;    Process efficiency;   

DOI  :  10.1016/j.jclepro.2016.05.138

来源: Elsevier

【 摘 要 】

Atomic Layer Deposition (ALD) technology has been under rapid development toward a broad array of applications, while the low deposition efficiency and heavy waste of TMA are limiting its industrial-scale applications. In this paper, a mathematical model is developed based on an experimental ALD of alumina process, and an optimization approach is then proposed to investigate the optimal ALD operating for the minimum TMA wastes and the maximum Al2O3 production under various conditions. Results show that the maximum TMA adsorption and alumina production cannot be achieved simultaneously, but sufficient H2O dosing can minimize the gap between them. The influence of substrate surface saturation condition and operating temperature is also investigated. Results quantitatively show that lower surface saturation condition requires more ALD cycles to improve the precursors' utilization efficiency, while the optimal ALD process can increase, the maximum alumina production from 2.7 x 10(-4) mol/m(2) to 7.5 x 10(-4) mol/m(2) with the temperature rise from 150 degrees C to 200 degrees C. Besides, it is found that the maximum production of both vertical bar-Al(CH3)(2) and alumina is influenced by their corresponding half-cycle duration, and sufficient treatment time can significantly improve the ALD process efficiency and reduce the total TMA waste. These insights into the minimum TMA waste and maximum production of surface products can guide the future design of ALD of alumina process with better efficiency and sustainability. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

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