Nano-CeO2/SiO2 as an efficient catalytic conversion of waste engine oil into liquid fuel

JOURNAL OF CLEANER PRODUCTION

卷:166

Article

Zandi-Atashbar, Navid¹  Ensafi, Ali Asghar¹  Ahoor, Amir Hooshmand² 

[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran

[2] Ferdowsi Univ Mashhad, Fac Sci, Mashhad, Iran

关键词: Waste engine oil;    Diesel fuel;    Experimental design;    CeO2/SiO2 catalyst;    Modeling;   

DOI  :  10.1016/j.jclepro.2017.08.103

来源: Elsevier

【 摘 要 】

Nowadays, discard of 24 million tons used diesel engine oil per year is a significant challenge for human health and environment. Thus, waste conversion into more valuable products like fuel can be the best solution. This work covered catalytic converting the waste engine oil into fuel, gas, and char products of pyrolysis, based on multivariate experimental design. Hence, nano-CeO2/SiO2, as a catalyst, was synthesized and characterized by different analytical methods. As the main aim of this work, this efficient catalyst is used to achieve low-level sulfur fuel from inexpensive, not eco-friendly and available waste engine oil. Thus, the ability of liquid product as a successfully applicable substitute for diesel fuel was also assessed. Furthermore, the modeling and optimization of pyrolytic fuel production based on the process factors, including operating temperature, the flow rate of argon, catalyst amount and time, were conducted. The properties of pyrolytic fuel produced in the optimizing conditions (554 degrees C, 128 mL min(-1) Ar, 8.8 wt% nano-CeO2/SiO2, and 95.0 min) were compared with commercial diesel fuels as represented flash point of 49.0 2.9 degrees C, the cetane number of 42.0 1.8, and gross calorific value of 44.9 3.2 MJ kg(-1). Moreover, application of nano-CeO2/SiO2 as the catalyst caused the reduction of sulfur level contained in pyrolytic fuel from 0.9 to 0.02 wt%. As the result of this research, catalytic pyrolysis of waste engine oil by nano-CeO2/SiO2 concluded rich liquid fuel product (60.7 wt%) with low sulfur (0.02 wt%) and inorganic pollutants (0.01 wt%) as diesel fuel. (C) 2017 Elsevier Ltd. All rights reserved.

【 授权许可】

Free