Comparison of electrochemical hydrogen storage and Coulombic efficiency of ZnAl2O4 and ZnAl2O4-impregnated TiO2 synthesized using green method

JOURNAL OF CLEANER PRODUCTION

卷:180

Article

Gholami, Tahereh¹  Salavati-Niasari, Masoud¹  Sabet, Mohammad²  Abbasi, Ali¹ 

[1] Univ Kashan, Inst Nano Sci & Nano Technol, POB 87317-51167, Kashan, Iran

[2] Valie e Asr Univ Rafsanjan, Fac Sci, Dept Chem, Rafsanjan, Iran

关键词: Nanocomposite;    Nanostructures;    Spinel;    Electrochemical hydrogen storage;    Coulombic efficiency;    Discharge capacity;   

DOI  :  10.1016/j.jclepro.2018.01.195

来源: Elsevier

【 摘 要 】

In this experimental work, we synthesized ZnAl2O4 and ZnAl2O4-TiO2 nanostructures with the help of two green reagents namely olive leaf and green tea extracts. We used different analysis to study the synthesized products. We utilized X-ray diffraction (XRD) patterns to study the crystal phase of the products. The chemical compositions of the products were characterized with energy dispersive X-ray spectroscopy (EDS) and Fourier transform infrared (FT-IR) analysis. In addition, we employed transmission electron microscopy (TEM) and scanning electron microscopy (SEM) images to study the size and morphology of products. The results showed the reagents have a meaningful effect on the product size and morphology because of their capping agent effect during the synthesis of the nanostructures. The porosity of samples was investigated by BET analysis. Based on our knowledge, for the first time, the electrochemical hydrogen storage and Columbic efficiency of ZnAl2O4 synthesized via essential oil of olive leaf and green tea were investigated via chronopotentiometry method in KOH (6 M) electrolyte. The results showed the synthesized nanocomposites of ZnAl2O4 with TiO2, improve the capacity of ZnAl2O4 spinel for the hydrogen storage. (C) 2018 Elsevier Ltd. All rights reserved.

【 授权许可】

Free