A multiphysics model that can capture crack patterns in Si thin films based on their microstructure

JOURNAL OF POWER SOURCES

卷:400

Article

Rethore, Julien¹  Zheng, Hao²  Li, Hong²  Li, Junjie²  Aifantis, Katerina E.^3,4 

[1] Univ Nantes, Ecole Cent Nantes, CNRS, Res Inst Civil & Mech Engn Gem,UMR 6183, F-44321 Nantes, France

[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China

[3] Univ Florida, Mech & Aerosp Engn, Tucson, AZ 85721 USA

[4] Togliatti State Univ, Mat Sci, Tolyatti, Russia

关键词: Si;    Anodes;    Li-ion batteries;    Phase field;    Fracture;   

DOI  :  10.1016/j.jpowsour.2018.07.106

来源: Elsevier

【 摘 要 】

Fracture in silicon anodes has fascinated the electrochemistry community for two decades, as it can result in a 80% capacity loss over the first few electrochemical cycles and is the limiting factor in commercializing such high capacity anodes. Although numerous experimental data exist illustrating severe fracture patterns and their dependence on the scale of the microstructure, no theoretical model has been able to re-produce and capture such behaviour. In this article, a multi-physics phase-field damage model is presented that can accurately capture the long standing problem of dry bed-lake crack patterns observed for Si thin film anodes. A promising aspect of the model is that, in addition to accounting for Li-ion diffusion, it can explicitly capture the microstructure, and therefore when applied to a Si film with a thickness below 100 nm no fracture was observed, which is consistent with experiments. As fracture in continuous thin films is random, micron-hole patterned Si films were also fabricated and cycled, resulting in ordered crack patterns. The proposed model was able to capture these elaborate, yet ordered, crack patterns, further validating its efficiency in predicting damage during lithiation of Si. This paves the way to using multiscale modeling for predicting the dimensions that limit and control fracture during lithiation, prolonging hence the electrode lifetime.

【 授权许可】

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