Lithium ion batteries made of electrodes with 99 wt% active materials and 1 wt% carbon nanotubes without binder or metal foils

JOURNAL OF POWER SOURCES

卷:321

Article

Hasegawa, Kei¹  Noda, Suguru¹ 

[1] Waseda Univ, Sch Adv Sci & Engn, Dept Appl Chem, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan

关键词: Lithium ion battery;    Carbon nanotube;    Binder free;    Three-dimensional current collector;    Laminate cell;   

DOI  :  10.1016/j.jpowsour.2016.04.130

来源: Elsevier

【 摘 要 】

Herein, we propose lithium ion batteries (LIBs) without binder or metal foils, based on a three-dimensional carbon nanotube (CNT) current collector. Because metal foils occupy 20-30 wt% of conventional LIBs and the polymer binder has no electrical conductivity, replacing such non-capacitive materials is a valid approach for improving the energy and power density of LIBs. Adding only 1 wt% of few-wall CNTs to the active material enables flexible freestanding sheets to be fabricated by simple dispersion and filtration processes. Coin cell tests are conducted on full cells fabricated from a 99 wt% LiCoO2-1 wt% CNT cathode and 99 wt% graphite-1 wt% CNT anode. Discharge capacities of 353 and 306 mAh g(graphite)(-1) are obtained at charge-discharge rates of 37.2 and 372 mA g(graphite)(-1) respectively, with a capacity retention of 65% at the 500th cycle. The suitability of the 1 wt% CNT-based composite electrodes for practical scale devices is demonstrated with laminate cells containing 50 x 50 mm(2) electrodes. Use of metal combs instead of metal foils enables charge-discharge operation of the laminate cell without considerable IR drop. Such electrodes will minimize the amount of metal and maximize the amount of active materials contained in LIBs. (C) 2016 Elsevier B.V. All rights reserved.

【 授权许可】

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